Succinic acid from renewable resources as a C4 building-block chemical-a review of the catalytic possibilities in aqueous media

被引：285

作者：

Delhomme, Clara ^{[1
]}

Weuster-Botz, Dirk ^{[1
]}

Kuehn, Fritz E. ^{[2
]}

机构：

[1] Tech Univ Munich, Inst Biochem Engn, D-85748 Garching, Germany

[2] Tech Univ Munich, Fac Chem, Chair Inorgan Chem & Mol Catalysis, D-85748 Garching, Germany

来源：

GREEN CHEMISTRY | 2009年 / 11卷 / 01期

关键词：

RUTHENIUM COMPLEXES; HYDROGENATION; WATER; REDUCTION; ANHYDRIDES; PHOSPHINE; KINETICS;

D O I：

10.1039/b810684c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aqueous hydrogenation of bio-based succinic acid has been reported for the production of value added chemicals, e. g. 1,4-butanediol, tetrahydrofuran, gamma-butyrolactone, 2- pyrrolidone or N-methyl-2-pyrrolidone. A variety of heterogeneous metallic catalysts, active under quite severe conditions have previously been studied, whereas research into organometallic complexes is thus far limited to solvent reactions or to aqueous reactions producing succinic acid.

引用

页码：13 / 26

页数：14

共 78 条

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