Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application

被引：2

作者：

Yano, Masafumi ^{[1
]}

Takemoto, Hidehiro ^{[1
]}

Tatsumi, Masakazu ^{[1
]}

Miyake, Hiroyuki ^{[2
]}

Tsukube, Hiroshi ^{[2
,3
]}

机构：

[1] Kansai Univ, Fac Chem Mat & Bioengn, Suita, Osaka 5648680, Japan

[2] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Sugimoto, Osaka 5588585, Japan

[3] Osaka City Univ, JST CREST, Sumiyoshi Ku, Osaka 5588585, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2012年 / 85卷 / 04期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

RARE-EARTH COMPLEXES; SOLVENT-EXTRACTION; MOLECULAR RECOGNITION; P-PHENYLENEDIAMINE; ADDUCT FORMATION; BETA-DIKETONES; X-RAY; ANION; LUMINESCENCE; TRIPOD;

D O I：

10.1246/bcsj.20110281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of two bridged bis(2-pyridylmethyl)amine-type ligands offered efficient separation of lanthanoid tris(beta-diketonates) complexes. The employed ligands bridged two lanthanoid tris(beta-diketonates) to form crystalline ternary complexes. Since the complexes containing larger lanthanoid centers were preferentially precipitated, the bridging ligands selectively recognized the lanthanoid tris(beta-diketonates) in the crystallization process, and offered an efficient separation method.

引用

页码：490 / 496

页数：7

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