Preferential Crystallization of Lanthanoid Tris(β-diketonates) with Bridged Bis(2-pyridylmethyl)amine Ligands toward Separation Application

被引：2
|
作者：
Yano, Masafumi [1 ]
Takemoto, Hidehiro [1 ]
Tatsumi, Masakazu [1 ]
Miyake, Hiroyuki [2 ]
Tsukube, Hiroshi [2 ,3 ]
机构：
[1] Kansai Univ, Fac Chem Mat & Bioengn, Suita, Osaka 5648680, Japan
[2] Osaka City Univ, Grad Sch Sci, Dept Chem, Sumiyoshi Ku, Sugimoto, Osaka 5588585, Japan
[3] Osaka City Univ, JST CREST, Sumiyoshi Ku, Osaka 5588585, Japan
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2012年 / 85卷 / 04期
基金：
日本学术振兴会; 日本科学技术振兴机构;
关键词：
RARE-EARTH COMPLEXES; SOLVENT-EXTRACTION; MOLECULAR RECOGNITION; P-PHENYLENEDIAMINE; ADDUCT FORMATION; BETA-DIKETONES; X-RAY; ANION; LUMINESCENCE; TRIPOD;
D O I：
10.1246/bcsj.20110281
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A combination of two bridged bis(2-pyridylmethyl)amine-type ligands offered efficient separation of lanthanoid tris(beta-diketonates) complexes. The employed ligands bridged two lanthanoid tris(beta-diketonates) to form crystalline ternary complexes. Since the complexes containing larger lanthanoid centers were preferentially precipitated, the bridging ligands selectively recognized the lanthanoid tris(beta-diketonates) in the crystallization process, and offered an efficient separation method.
引用
收藏
页码：490 / 496
页数：7
相关论文
共 50 条
  • [21] Syntheses, structures, and O2-reactivities of copper(I) complexes with bis(2-pyridylmethyl)amine and bis(2-quinolylmethyl)amine tridentate ligands
    Kunishita, Atsushi
    Osako, Takao
    Tachi, Yoshimitsu
    Teraoka, Junji
    Itoh, Shinobu
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2006, 79 (11) : 1729 - 1741
  • [22] Syntheses, structures, and O2-reactivities of copper(I) complexes with bis(2-pyridylmethyl)amine and bis(2-quinolylmethyl)amine tridentate ligands
    Kunishita, Atsushi
    Osako, Takao
    Tachi, Yoshimitsu
    Teraoka, Junji
    Itoh, Shinobu
    Bulletin of the Chemical Society of Japan, 2006, 79 (11): : 1729 - 1741
  • [23] Synthesis and characterization of ruthenium(II)-nitrile complexes with bisamide-tpa ligands (tpa = tris(2-pyridylmethyl)amine)
    Kojima, T. (cosyscc@mbox.nc.kyushu-u.ac.jp), 1600, Chemical Society of Japan (78):
  • [24] Synthesis and characterization of ruthenium(II)-nitrile complexes with bisamide-tpa ligands (tpa = tris(2-pyridylmethyl)amine)
    Kojima, T
    Hayashi, KI
    Shiota, Y
    Tachi, Y
    Naruta, Y
    Suzuki, T
    Uezu, K
    Yoshizawa, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2005, 78 (12) : 2152 - 2158
  • [25] RETRACTED: μ-oxido-bis{chlorido[tris(2-pyridylmethyl)amine]iron(III)} bis(hexafluorido-phosphate) (Retracted Article)
    Liu, Ying
    Dou, Jianmin
    Li, Dacheng
    Zhang, Xianxi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2722 - U836
  • [26] New tridentate ligands of the type N-alkyl-N,N-bis(2-pyridylmethyl)amine
    Dick, S
    Weiss, A
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (02): : 188 - 192
  • [27] Tris(2-pyridylmethyl)amine Based Ligands in Copper Catalyzed Atom Transfer Radical Addition (ATRA) and Polymerization (ATRP)
    Pintauer, Tomislav
    CONTROLLED RADICAL POLYMERIZATION, VOL 1: MECHANISMS, 2015, 1187 : 105 - 128
  • [28] Tridentate coordination of monosubstituted derivatives of the tris(2-pyridylmethyl)amine ligand to FeCl3:: Structures and spectroscopic properties of ((2-bromopyridyl)methyl)bis(2-pyridylmethyl)amine FeIIICl3 and (((2-p-methoxyphenyl)pyridyl)methyl)Bis(2-pyridyl- methyl)]amine FeIIICl3 and comparison with the bis(2-pyridylmethyl)]amine FeIIICl3 complex
    Mandon, D
    Nopper, A
    Litrol, T
    Goetz, S
    INORGANIC CHEMISTRY, 2001, 40 (18) : 4803 - 4806
  • [29] SYNTHESES AND CHARACTERIZATION OF BINUCLEAR MANGANESE(III,IV) AND MANGANESE(IV,IV) COMPLEXES WITH LIGANDS RELATED TO TRIS(2-PYRIDYLMETHYL)AMINE
    OKI, AR
    GLERUP, J
    HODGSON, DJ
    INORGANIC CHEMISTRY, 1990, 29 (13) : 2435 - 2441
  • [30] From mononuclear to polynuclear: copper and zinc complexes obtained from polypyridylamine ligands related to tris(2-pyridylmethyl)-amine (tmpa)
    Beitat, Alexander
    Becker, Jonathan
    Xu, Jing-Yuan
    Brombach, Christoph-Cornelius
    Becker, Sabine
    Kelm, Harald
    Walter, Olaf
    Wuertele, Christian
    Schindler, Siegfried
    JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (11-13) : 1875 - 1893
12345