Synthesis of lanthanocene amides and their applications as single-component initiators in polymerization of polar monomers

被引：0

作者：

Shen, Q ^{[1
]}

Yao, YM ^{[1
]}

机构：

[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2001年 / 21卷 / 11期

关键词：

lanthanocene amide; synthesis; polar monomer; catalysis; polymerization;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This article describes our research results in recent years on the synthesis, molecular structure of lanthanocene amides and their applications in the polymerization of polar monomers, including methyl methacrylate, (dimethylamino) ethyl methacrylate, and phenyl isocyanate and ring-opening polymerization of epsilon-caprolactone, as well. The relationship between the structures of lanthanocene amides and catalytic activities was discussed, and the polymerization mechanism was suggested.

引用

页码：1018 / 1023

页数：6

共 31 条

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