Induced-fit recognition by p-carboxylatocalix[4]arene hosts

被引：16

作者：

Pierro, Teresa ^{[1
]}

Gaeta, Carmine ^{[1
]}

Troisi, Francesco ^{[1
]}

Neri, Placido ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84084 Salerno, Italy

来源：

TETRAHEDRON LETTERS | 2009年 / 50卷 / 03期

关键词：

Calixarenes; p-Carboxylatocalixarenes; Paraquat; Induced-fit; NMR titrations; DOSY experiments; CONFORMATIONAL TEMPLATION; UPPER RIM; CONE; CALIXARENES; MOLECULES; ISOMERISM;

D O I：

10.1016/j.tetlet.2008.11.016

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Calix[4]arene derivatives bearing anionic carboxylato groups at the upper rim (p-carboxylatocalix[4]arenes) are able to 'grab' paraquat dicationic guest through an induced-fit mechanism, which originates from the conformational mobility of calixarene skeleton. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：350 / 353

页数：4

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