Synthesis and reactivity of organolanthanoid complexes containing N and S ligands

被引：27

作者：

Shen, Q ^{[1
]}

Yao, YM

机构：

[1] Suzhou Univ, Dept Chem & Chem Engn, Suzhou 215006, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 647卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

organolanthanoid complex; synthesis; reactivity; activation small molecule; polymerization;

D O I：

10.1016/S0022-328X(01)01478-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper provides a brief account of our recent researches in organolanthanoid chemistry containing N and S ligands. The first is concerned with the synthesis of organolanthanoid complexes, including anionic, supramolecular, neutral organolanthanoid amides and the organolanthanoid complexes supported by beta-diketiminate, as well as organolanthanoid thiolates. The second deals with the reactivity of these organolanthanoid complexes, including the reaction with phenyl isocyanate, CS2, and phenyl isothiocyanate, and the catalytic activity for the polymerization of polar monomers, such as methyl methacrylate, (dimethylamino)ethyl methacrylate and epsilon-caprolactone. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：180 / 189

页数：10

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