Advanced materials and technologies for supercapacitors used in energy conversion and storage: a review

被引：356

作者：

Maksoud, M. I. A. Abdel ^{[1
]}

Fahim, Ramy Amer ^{[2
]}

Shalan, Ahmed Esmail ^{[3
,4
]}

Abd Elkodous, M. ^{[5
,6
]}

Olojede, S. O. ^{[7
]}

Osman, Ahmed, I ^{[8
]}

Farrell, Charlie ^{[9
,10
]}

Al-Muhtaseb, Ala'a H. ^{[11
]}

Awed, A. S. ^{[12
]}

Ashour, A. H. ^{[1
]}

Rooney, David W. ^{[8
]}

机构：

[1] Atom Energy Author, Radiat Phys Dept, Mat Sci Lab, Natl Ctr Radiat Res & Technol NCRRT, Cairo, Egypt

[2] Atom Energy Author, Radiat Protect & Dosimetry Dept, Natl Ctr Radiat Res & Technol NCRRT, Cairo, Egypt

[3] Cent Met Res & Dev Inst CMRDI, POB 87, Cairo 11421, Egypt

[4] Univ Basque Country, BCMat Basque Ctr Mat Applicat & Nanostruct, Sci Pk,Barrio Sarriena S-N, Leioa 48940, Spain

[5] Toyohashi Univ Technol, Dept Elect & Elect Informat Engn, Toyohashi, Aichi 4418580, Japan

[6] Nile Univ, Ctr Nanotechnol CNT, Sch Engn & Appl Sci, Giza 16453, Egypt

[7] Univ KwaZulu Natal, Nanotechnol Platforms, Durban, South Africa

[8] Queens Univ Belfast, Sch Chem & Chem Engn, David Keir Bldg,Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland

[9] South West Coll, Cookstown BT80 8DN, Tyrone, North Ireland

[10] Queens Univ Belfast, Sch Mech & Aerosp Engn, Belfast BT9 5AH, Antrim, North Ireland

[11] Sultan Qaboos Univ, Coll Engn, Dept Petr & Chem Engn, Muscat, Oman

[12] Higher Inst Engn & Technol, Manzala, Egypt

来源：

ENVIRONMENTAL CHEMISTRY LETTERS | 2021年 / 19卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

Supercapacitor; Magnetic oxides; Transition metals sulfides; Carbon materials; Conducting polymer materials; HIGH-PERFORMANCE SUPERCAPACITOR; REDUCED GRAPHENE OXIDE; NITROGEN-DOPED GRAPHENE; ENHANCED ELECTROCHEMICAL PROPERTIES; FACILE HYDROTHERMAL SYNTHESIS; COBALT FERRITE NANOPARTICLES; NEGATIVE-ELECTRODE MATERIALS; LOW-COST SUPERCAPACITORS; SHELL NANOWIRE ARRAYS; SODIUM-ION BATTERIES;

D O I：

10.1007/s10311-020-01075-w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Supercapacitors are increasingly used for energy conversion and storage systems in sustainable nanotechnologies. Graphite is a conventional electrode utilized in Li-ion-based batteries, yet its specific capacitance of 372 mA h g(-1)is not adequate for supercapacitor applications. Interest in supercapacitors is due to their high-energy capacity, storage for a shorter period and longer lifetime. This review compares the following materials used to fabricate supercapacitors: spinel ferrites, e.g., MFe2O4, MMoO(4)and MCo(2)O(4)where M denotes a transition metal ion; perovskite oxides; transition metals sulfides; carbon materials; and conducting polymers. The application window of perovskite can be controlled by cations in sublattice sites. Cations increase the specific capacitance because cations possess large orbital valence electrons which grow the oxygen vacancies. Electrodes made of transition metal sulfides, e.g., ZnCo2S4, display a high specific capacitance of 1269 F g(-1), which is four times higher than those of transition metals oxides, e.g., Zn-Co ferrite, of 296 F g(-1). This is explained by the low charge-transfer resistance and the high ion diffusion rate of transition metals sulfides. Composites made of magnetic oxides or transition metal sulfides with conducting polymers or carbon materials have the highest capacitance activity and cyclic stability. This is attributed to oxygen and sulfur active sites which foster electrolyte penetration during cycling, and, in turn, create new active sites.

引用

页码：375 / 439

页数：65

共 524 条

[1] Investigation of structural and magnetic properties of multiferroic La1-xYxFeO3 Perovskites, prepared by citrate auto-combustion technique [J].