Synthesis of N,N,N-Trimethyl-1-adamantyl Quaternary Ammonium Hydroxide and Technology Development

被引：0

作者：

Hu Jian ^{[1
]}

Yang Fangwen ^{[2
]}

Huang Minggang ^{[1
]}

机构：

[1] Sichuan Coll Chem Technol, Dept Chem Engn, Luzhou, Peoples R China

[2] Sichuan Coll Chem Technol, Dept Pharm & Environm Engn, Luzhou, Peoples R China

来源：

CHEMICAL ENGINEERING AND MATERIAL PROPERTIES, PTS 1 AND 2 | 2012年 / 391-392卷

关键词：

Adamantane; Adamantyl quaternary ammonium salts; Synthesis; Adamantyl quaternary ammonium hydroxide; Eschweiler-Clarke reaction; ADAMANTANE; SURFACTANTS; POLYIMIDES;

D O I：

10.4028/www.scientific.net/AMR.391-392.1159

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

N,N-dimethyl-1-adamantane was synthesized from amantadine through Eschweiler-Clarke reaction, The optimal ratio of amantadine, formic acid and formaldehyde was 1:5:4, and the reaction time was 18 h at 98 degrees C. The product yield was 93.4% on these conditions. N,N,N-trimethyl-1-adamantyl quaternary ammonium salt then was synthesized, the product yield was 90.5%, succeeding eco-friendly procedure technology was developed. N,N,N-trimethyl-1-adamantyl quaternary ammonium hydroxide was obtained finally, target product yield was 84.3%. The structure of compounds were characterized by H-1 NMR, C-13 NMR, MS and GC-MS.

引用

页码：1159 / +

页数：2

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