Synthesis of N,N,N-Trimethyl-1-adamantyl Quaternary Ammonium Hydroxide and Technology Development

被引：0

作者：

Hu Jian ^{[1
]}

Yang Fangwen ^{[2
]}

Huang Minggang ^{[1
]}

机构：

[1] Sichuan Coll Chem Technol, Dept Chem Engn, Luzhou, Peoples R China

[2] Sichuan Coll Chem Technol, Dept Pharm & Environm Engn, Luzhou, Peoples R China

来源：

CHEMICAL ENGINEERING AND MATERIAL PROPERTIES, PTS 1 AND 2 | 2012年 / 391-392卷

关键词：

Adamantane; Adamantyl quaternary ammonium salts; Synthesis; Adamantyl quaternary ammonium hydroxide; Eschweiler-Clarke reaction; ADAMANTANE; SURFACTANTS; POLYIMIDES;

D O I：

10.4028/www.scientific.net/AMR.391-392.1159

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

N,N-dimethyl-1-adamantane was synthesized from amantadine through Eschweiler-Clarke reaction, The optimal ratio of amantadine, formic acid and formaldehyde was 1:5:4, and the reaction time was 18 h at 98 degrees C. The product yield was 93.4% on these conditions. N,N,N-trimethyl-1-adamantyl quaternary ammonium salt then was synthesized, the product yield was 90.5%, succeeding eco-friendly procedure technology was developed. N,N,N-trimethyl-1-adamantyl quaternary ammonium hydroxide was obtained finally, target product yield was 84.3%. The structure of compounds were characterized by H-1 NMR, C-13 NMR, MS and GC-MS.

引用

页码：1159 / +

页数：2

共 50 条

[1] Influence of the N,N,N-Trimethyl-1-adamantyl Ammonium Structure-Directing Agent on Al Substitution in SSZ-13 Zeolite
Li, Sichi
Gounder, Rajamani
Debellis, Anthony
Mueller, Imke B.
Prasad, Subramanian
Moini, Ahmad
Schneider, William F.
JOURNAL OF PHYSICAL CHEMISTRY C, 2019, 123 (28): : 17454 - 17458
[2] Influence of an N,N,N-Trimethyl-1-adamantyl Ammonium (TMAda plus ) Structure Directing Agent on Al Distributions and Pair Features in Chabazite Zeolite
Wang, Xiaoyu
Wang, Yujia
Moini, Ahmad
Gounder, Rajamani
Maginn, Edward J.
Schneider, William F.
CHEMISTRY OF MATERIALS, 2022, 34 (24) : 10811 - 10822
[3] N,N,N-TRIMETHYL-1-ADAMANTYLAMMONIUM FLUORIDE, A COMPLETELY ANHYDROUS QUATERNARY AMMONIUM FLUORIDE SALT
HARMON, KM
SOUTHWORTH, BA
WILSON, KE
KEEFER, PK
JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (25): : 7294 - 7295
[4] THERMOLYSIS OF "N,N,N-TRIMETHYL-1-ADAMANTYLAMMONIUM HYDROXIDE
ADAMS, BL
LIU, JH
KOVACIC, P
TETRAHEDRON LETTERS, 1974, (05) : 427 - 428
[5] Quaternary ammonium salt N-(dodecyloxycarboxymethyl)-N,N,N-trimethyl ammonium chloride induced alterations in Saccharomyces cerevisiae physiology
Ewa Obłąk
Agata Piecuch
Ewa Maciaszczyk-Dziubińska
Donata Wawrzycka
Journal of Biosciences, 2016, 41 : 601 - 614
[6] Quaternary ammonium salt N-(dodecyloxycarboxymethyl)-N,N,N-trimethyl ammonium chloride induced alterations in Saccharomyces cerevisiae physiology
Oblak, Ewa
Piecuch, Agata
Maciaszczyk-Dziubinska, Ewa
Wawrzycka, Donata
JOURNAL OF BIOSCIENCES, 2016, 41 (04) : 601 - 614
[7] The physiological and morphological phenotype of a yeast mutant resistant to the quaternary ammonium salt N-(dodecyloxycarboxymethyl)-N,N,N-trimethyl ammonium chloride
Ewa Obłąk
Andrzej Gamian
Ryszard Adamski
Stanisław Ułaszewski
Cellular & Molecular Biology Letters, 2010, 15 : 215 - 233
[8] The physiological and morphological phenotype of a yeast mutant resistant to the quaternary ammonium salt N-(dodecyloxycarboxymethyl)-N,N,N-trimethyl ammonium chloride
Oblak, Ewa
Gamian, Andrzej
Adamski, Ryszard
Ulaszewski, Stanislaw
CELLULAR & MOLECULAR BIOLOGY LETTERS, 2010, 15 (02) : 215 - 233
[9] PYROLYSIS OF N,N,N-TRIMETHYL-3-HOMOADAMANTYLAMMONIUM HYDROXIDE
ADAMS, BL
KOVACIC, P
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1973, (AUG26): : 21 - 21
[10] SYNTHESIS OF N-ADAMANTYL-N'-METHYLPYRIDYLTHIOUREAS
SKWARSKI, D
KALINOWSKATORZ, J
MUSIAL, E
SENCZUK, L
SOBIAK, S
SOBOLEWSKI, H
ACTA POLONIAE PHARMACEUTICA, 1984, 41 (04): : 447 - 450

← 1 2 3 4 5 →