A convenient synthesis of 3,4-disubstituted-1,2,4-thiadiazole-5(4H)-thiones

被引：6

作者：

Agirbas, H ^{[1
]}

Kahraman, K ^{[1
]}

机构：

[1] Kocaeli Univ, Dept Chem, TR-41300 Izmit, Turkey

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1998年 / 134卷

关键词：

1,2,4-oxadiazole-5-thione; 1,2,4-thiadiazole-5-one; 1,2,4-thiadiazole-5-thione;

D O I：

10.1080/10426509808545478

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3,4-Disubstituted-1,2,4-oxadiazole-5(4H)-ones were obtained from the reaction of substituted amide oximes with ethylchloroformate. These compounds were treated with P2S5 to give corresponding 1,2,4-oxadiazole-5-thiones. Rearrangement of 1,2,4-oxadiazole-5-thiones, catalysed by metallic copper, yielded 1,2,4-thiadiazole-5-ones. The reaction of 1,2,4-thiadiazole-5-ones with P2S5 gave 1,2,4-thiadiazole-5-thiones.

引用

页码：381 / 389

页数：9