A porous metal-organic framework based on Zn6O2 clusters: chemical stability, gas adsorption properties and solvatochromic behavior

被引：117
作者：
Cui, Jiehu [1 ]
Li, Yizhi [1 ]
Guo, Zijian [1 ]
Zheng, Hegen [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 06期
关键词：
HYDROGEN STORAGE; POROSITY; LUMINESCENCE; INCLUSION; MOLECULES; POLYMER; SITES;
D O I：
10.1039/c2cc36713k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A highly connected 3D metal-organic framework with tfz-d topology based on Zn6O2 clusters and flexible carboxylate ligands has been synthesized. The obtained Zn-MOF shows solvatochromic behavior for fluorescence sensing of small molecules, gas adsorption properties and exceptional chemical stability and might have applications for separation and detection purposes.
引用
收藏
页码：555 / 557
页数：3
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