Synthesis, crystal structure and magnetic properties of a new [Zn6IIDy6III] dodecanuclear motif

被引：10

作者：

Dinca, Alina S. ^{[1
]}

Vallejo, Julia ^{[2
]}

Shova, Sergiu ^{[3
]}

Lloret, Francesc ^{[2
]}

Julve, Miguel ^{[2
]}

Andruh, Marius ^{[1
]}

机构：

[1] Univ Bucharest, Fac Chem, Inorgan Chem Lab, Bucharest 020464, Romania

[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, Inst Ciencia Mol, Valencia 46980, Spain

[3] Petru Poni Inst Macromol Chem, RO-700487 Iasi, Romania

来源：

POLYHEDRON | 2013年 / 65卷

关键词：

Heterometallic complexes; Zinc complexes; Dysprosium complexes; Single ion magnets; SINGLE-CHAIN MAGNETS; HETEROBINUCLEAR COMPLEX; MOLECULE MAGNETS; RELAXATION; BEHAVIOR; LIGAND; FAMILY;

D O I：

10.1016/j.poly.2013.08.049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dodecanuclear complex, [{(HL)(L)(dmf)(ZnDyIII)-Dy-II(dmf)(H2O)}(6)]center dot 3dmf4 center dot 2H(2)O has been assembled using a supramolecular compartmental ligand (H3L results from the condensation reaction of 3-formylsalicylic acid and hydroxylamine). The six Dy-III ions describe an octahedron that is inscribed into the octahedron generated by the zinc(II) ions each Dy-III ion from this motif behaving as a single ion magnet. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：238 / 243

页数：6

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