Application of Taguchi method for optimization of process parameters in decalcification of samarium-cobalt intermetallic powder

被引：10

作者：

Dasgupta, Kinshuk ^{[1
]}

Singh, D. K. ^{[1
]}

Sahoo, D. K. ^{[1
]}

Anitha, M. ^{[1
]}

Awasthi, A. ^{[2
]}

Singh, H. ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Mat Grp, Rare Earths Dev Sect, Bombay 400085, Maharashtra, India

[2] Bhabha Atom Res Ctr, Mat Proc Div, Bombay 400085, Maharashtra, India

来源：

SEPARATION AND PURIFICATION TECHNOLOGY | 2014年 / 124卷

关键词：

Decalcification; Taguchi method; Samarium-cobalt intermetallic; X-ray diffraction; Scanning electron microscopy;

D O I：

10.1016/j.seppur.2013.12.041

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Decalcification studies on samarium-cobalt intermetallic alloy powder produced by reduction-diffusion process have been carried out under wide range of experimental conditions based on Taguchi method. This approach has been adopted to arrive at optimum conditions for the leaching operation for calcium removal without affecting the yield of Sm2Co17. The percentage effect of number of water wash, acid wash, pH and digestion time on decalcification was investigated. Conditions predicted by Taguchi method successfully brought down the residual calcium value to about 1750 ppm in Sm2Co17 suitable for further operation related to making permanent magnet. The Sm2Co17 phase was found to be stable even after long period of leaching operations as characterized by scanning electron microscopy and X-ray diffraction. Leaching of calcium from large batch product samples have been demonstrated successfully with 99.5% yield and residual calcium in the range of 1740-1750 ppm. Acetic acid and propionic acid showed comparable results in decalcification. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：74 / 80

页数：7

共 23 条

[1]

Adler Y., 1975, DESIGN EXPT FIND OPT

[2]

Arendt R. H., 1975, U.S. Patent, Patent No. [3,912,554, 3912554]

[3] Exchange Coupled Nd2Fe14B/α-Fe Nanocomposite by Novel Autocombustion-Reduction Diffusion Synthesis [J].

Bhame, Shekar D. ;

Swaminathan, V. ;

Deheri, Pratap K. ;

Ramanujan, Raju V. .

ADVANCED SCIENCE LETTERS, 2010, 3 (02) :174-179

[4] Developments in the processing and properties of NdFeb-type permanent magnets [J].

Brown, D ;

Ma, BM ;

Chen, ZM .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2002, 248 (03) :432-440

[5]

Camp F. E., 1991, US Patent, Patent No. [4,990,307, 4990307]

[6]

Campbell P., 1994, PERMANENT MAGNET MAT

[7]

CECH RE, 1974, JOM-J MET, V26, P32

[8] Optimization of microwave-assisted solvent extraction of polycyclic aromatic hydrocarbons in marine sediments using a microwave extraction system with high-performance liquid chromatography fluorescence detection and gas chromatography mass spectrometry [J].

Chee, KK ;

Wong, MK ;

Lee, HK .

JOURNAL OF CHROMATOGRAPHY A, 1996, 723 (02) :259-271

[9]

Chen C. J., 1991, US Patent, Patent No. [5,064,465, 5064465]

[10] Optimization of Parameters by Taguchi Method for Controlling Purity of Carbon Nanotubes in Chemical Vapour Deposition Technique [J].

Dasgupta, K. ;

Sen, D. ;

Mazumder, S. ;

Basak, C. B. ;

Joshi, J. B. ;

Banerjee, S. .

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2010, 10 (06) :4030-4037

← 1 2 3 →