Palladium-catalyzed selective defluorinative sulfenylation for the synthesis of fluorovinylthioethers

被引：12
|
作者：
He, Shi-Yu [1 ]
Zhang, Xing-Guo [1 ,2 ]
机构：
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[2] Hezhou Univ, Guangxi Key Lab Calcium Carbonate Resources Compr, Hezhou 542899, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2020年 / 7卷 / 20期
关键词：
F BOND ACTIVATION; GEM-DIFLUOROALKENES; LEWIS-ACID; FLUORINE; HYDRODEFLUORINATION; FLUOROALKENES; FUNCTIONALIZATION; TRIFLUOROTOLUENES; CLEAVAGE;
D O I：
10.1039/d0qo00818d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient transformation of trifluoromethylated compounds to monofluoroalkenes was developed through Pd-catalyzed selective defluorinative sulfenylation. A variety of alpha-fluorovinylthioethers were prepared in good yields from alpha-trifluoromethylated benzyl bromides and odorless disulfides.
引用
收藏
页码：3174 / 3178
页数：5
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