Electrochemical methods for determining ionic charge in solids

被引：9
作者：
De Souza, Roger A. [1 ]
Mueller, David N. [2 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Phys Chem, Aachen, Germany
[2] Forschungszentrum Julich, Peter Grunberg Inst, Julich, Germany
来源：
NATURE MATERIALS | 2021年 / 20卷 / 04期
关键词：
ELECTRONIC-TRANSPORT; DEFECT STRUCTURE; NONSTOICHIOMETRY; CONDUCTIVITY; CELLS;
D O I：
10.1038/s41563-020-0790-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Classical experiments from solid-state electrochemistry can be used to determine the charge of ions in solids. This Comment also clarifies how the charge of point defects fits with the standard picture of ionic charge, and highlights differences between these electrochemical experiments and methods that probe electrons directly.
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收藏
页码：443 / 446
页数：4
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