Electrochemical methods for determining ionic charge in solids

被引：10

作者：

De Souza, Roger A. ^{[1
]}

Mueller, David N. ^{[2
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Phys Chem, Aachen, Germany

[2] Forschungszentrum Julich, Peter Grunberg Inst, Julich, Germany

来源：

NATURE MATERIALS | 2021年 / 20卷 / 04期

关键词：

ELECTRONIC-TRANSPORT; DEFECT STRUCTURE; NONSTOICHIOMETRY; CONDUCTIVITY; CELLS;

D O I：

10.1038/s41563-020-0790-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Classical experiments from solid-state electrochemistry can be used to determine the charge of ions in solids. This Comment also clarifies how the charge of point defects fits with the standard picture of ionic charge, and highlights differences between these electrochemical experiments and methods that probe electrons directly.

引用

页码：443 / 446

页数：4

共 29 条

[1] CONTROLLED-VALENCE PROPERTIES OF LA1-XSRXFEO3 AND LA1-XSRXMNO3 STUDIED BY SOFT-X-RAY ABSORPTION-SPECTROSCOPY [J].

ABBATE, M ;

DEGROOT, FMF ;

FUGGLE, JC ;

FUJIMORI, A ;

STREBEL, O ;

LOPEZ, F ;

DOMKE, M ;

KAINDL, G ;

SAWATZKY, GA ;

TAKANO, M ;

TAKEDA, Y ;

EISAKI, H ;

UCHIDA, S .

PHYSICAL REVIEW B, 1992, 46 (08) :4511-4519

[2]

[Anonymous], 1834, PHILOS T R SOC LOND, DOI [DOI 10.1098/RSTL.1834.0008, 10.1098/rstl.1834.0008]

[3] A REINTERPRETATION OF THE DEFECT STRUCTURE OF L-TA2O5 [J].

BREDESEN, R ;

KOFSTAD, P .

SOLID STATE IONICS, 1988, 27 (1-2) :11-18

[4]

BROUWER G, 1954, PHILIPS RES REP, V9, P366

[5] c-Axis Dimer and Its Electronic Breakup: The Insulator-to-Metal Transition in Ti2O3 [J].

Chang, C. F. ;

Koethe, T. C. ;

Hu, Z. ;

Weinen, J. ;

Agrestini, S. ;

Zhao, L. ;

Gegner, J. ;

Ott, H. ;

Panaccione, G. ;

Wu, Hua ;

Haverkort, M. W. ;

Roth, H. ;

Komarek, A. C. ;

Offi, F. ;

Monaco, G. ;

Liao, Y. -F. ;

Tsuei, K. -D. ;

Lin, H. -J. ;

Chen, C. T. ;

Tanaka, A. ;

Tjeng, L. H. .

PHYSICAL REVIEW X, 2018, 8 (02)

[6] ELECTRONIC-TRANSPORT BEHAVIOR IN SINGLE-CRYSTALLINE BA0.03SR0.97TIO3 [J].

CHOI, GM ;

TULLER, HL ;

GOLDSCHMIDT, D .

PHYSICAL REVIEW B, 1986, 34 (10) :6972-6979

[7] COBALTOUS OXIDE POINT-DEFECT STRUCTURE AND NONSTOICHIOMETRY, ELECTRICAL-CONDUCTIVITY, COBALT TRACER DIFFUSION [J].

DIECKMANN, R .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1977, 107 (02) :189-210

[8] MEASUREMENT AND REGULATION OF OXYGEN-CONTENT IN GASES USING SOLID ELECTROLYTE CELLS .3. OXYGEN PUMP-GAUGE [J].

FOULETIER, J ;

VITTER, G ;

KLEITZ, M .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1975, 5 (02) :111-120

[9] Core-level photoemission measurements of the chemical potential shift as a probe of correlated electron systems [J].

Fujimori, A ;

Ino, A ;

Matsuno, J ;

Yoshida, T ;

Tanaka, K ;

Mizokawa, T .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2002, 124 (2-3) :127-138

[10] CATION SELF-DIFFUSION IN CR2O3 [J].

HOSHINO, K ;

PETERSON, NL .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1983, 66 (11) :C202-C203

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