Supramolecular architecture of self-adhesive calix[4]arene thiourea derivative by hydrogen bonding and π-π interactions

被引：6
作者：
Zhao, BT [1 ]
Liu, Y
Zhang, HY
机构：
[1] Luoyang Teachers Coll, Dept Chem, Luoyang 471022, Peoples R China
[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 691卷 / 1-3期
关键词：
calix[4]arene thiourea derivative; supramolecular architecture; hydrogen bonding; pi-pi interaction;
D O I：
10.1016/j.molstruc.2003.10.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two calix[4]arene thiourea derivative 2 and 3 have been prepared by the reaction of the easily accessible 1,3-distally substituted calix[4]arene amine 1 with the corresponding isothiocyanate in dry CH2O2 with satisfactory yield. The single crystal of 2 was prepared, and X-ray crystallographic analysis clearly revealed that the interleaving 2D supramolecular architecture formed by synergic hydrogen bonding and pi-pi interactions. (C) 2003 Published by Elsevier B.V.
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收藏
页码：25 / 31
页数：7
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