Supramolecular architecture of self-adhesive calix[4]arene thiourea derivative by hydrogen bonding and π-π interactions

被引：6
作者：
Zhao, BT [1 ]
Liu, Y
Zhang, HY
机构：
[1] Luoyang Teachers Coll, Dept Chem, Luoyang 471022, Peoples R China
[2] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2004年 / 691卷 / 1-3期
关键词：
calix[4]arene thiourea derivative; supramolecular architecture; hydrogen bonding; pi-pi interaction;
D O I：
10.1016/j.molstruc.2003.10.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two calix[4]arene thiourea derivative 2 and 3 have been prepared by the reaction of the easily accessible 1,3-distally substituted calix[4]arene amine 1 with the corresponding isothiocyanate in dry CH2O2 with satisfactory yield. The single crystal of 2 was prepared, and X-ray crystallographic analysis clearly revealed that the interleaving 2D supramolecular architecture formed by synergic hydrogen bonding and pi-pi interactions. (C) 2003 Published by Elsevier B.V.
引用
收藏
页码：25 / 31
页数：7
相关论文
共 33 条
  • [1] Self-assembled hydrogen-bonded molecular cages of calix[6]arenetricarboxylic acid derivatives
    Arduini, A
    Domiano, L
    Ogliosi, L
    Pochini, A
    Secchi, A
    Ungaro, R
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (22) : 7866 - 7868
  • [2] Brody MS, 1999, ANGEW CHEM INT EDIT, V38, P1640, DOI 10.1002/(SICI)1521-3773(19990601)38:11<1640::AID-ANIE1640>3.0.CO
  • [3] 2-Y
  • [4] Contribution to activity of histidine-aromatic, amide-aromatic, and aromatic-aromatic interactions in the extended catalytic site of cysteine proteinases
    Bromme, D
    Bonneau, PR
    Purisima, E
    Lachance, P
    Hajnik, S
    Thomas, DY
    Storer, AC
    [J]. BIOCHEMISTRY, 1996, 35 (13) : 3970 - 3979
  • [5] Interconnective host-guest complexation of β-cyclodextrin-calix[4]arene couples
    Bügler, J
    Sommerdijk, NAJM
    Visser, AJWG
    van Hoek, A
    Nolte, RJM
    Engbersen, JFJ
    Reinhoudt, DN
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (01) : 28 - 33
  • [6] AROMATIC-AROMATIC INTERACTION - A MECHANISM OF PROTEIN-STRUCTURE STABILIZATION
    BURLEY, SK
    PETSKO, GA
    [J]. SCIENCE, 1985, 229 (4708) : 23 - 28
  • [7] CANTELLANO RK, 1998, J AM CHEM SOC, V120, P3657
  • [8] Chiral capsules: Asymmetric binding in calixarene-based dimers
    Castellano, RK
    Kim, BH
    Rebek, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (51) : 12671 - 12672
  • [9] Expanded calix[4]arene tetraurea capsules
    Cho, YL
    Rudkevich, DM
    Rebek, J
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) : 9868 - 9869
  • [10] Collins E. M., 1991, J CHEM SOC PERK T, V1, P3137
1234