Nano-TaOxNy particles synthesized from oxy-tantalum phthalocyanine: how to prepare precursors to enhance the oxygen reduction reaction activity after ammonia pyrolysis?

被引:20
作者
Chisaka, M. [1 ]
Ishihara, A. [2 ,3 ]
Uehara, N. [2 ]
Matsumoto, M. [4 ]
Imai, H. [4 ]
Ota, K. [2 ]
机构
[1] Hirosaki Univ, Elect & Informat Technol Dept, Hirosaki, Aomori 0368561, Japan
[2] Yokohama Natl Univ, Green Hydrogen Res Ctr, Hodogaya ku, Yokohama, Kanagawa 2408501, Japan
[3] Yokohama Natl Univ, Inst Adv Sci, Hodogaya ku, Yokohama, Kanagawa 2408501, Japan
[4] NISSAN ARC Ltd, Device Funct Anal Dept, Yokosuka, Kanagawa 2370061, Japan
关键词
FUEL-CELL; CARBON NANOTUBES; OXIDE; TA3N5; FILMS; CATALYST; SURFACE; PEFC; PEROVSKITE; DEPOSITION;
D O I
10.1039/c5ta03860j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Nano-TaOxNy oxygen reduction reaction (ORR) catalysts were supported on multi-walled carbon nanotubes (MWCNTs) using two-step pyrolysis of oxy-tantalum phthalocyanine (TaOPc). For the first time, slightly oxidized Ta3N5 has been experimentally proposed to be ORR active in acidic media.
引用
收藏
页码:16414 / 16418
页数:5
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