Anhydride-functionalized fullerene: a versatile precursor for fullerene-based materials

被引：4
|
作者：
Heo, Gyu Seong [1 ]
Moon, Bongjin [1 ]
机构：
[1] Sogang Univ, Dept Chem, Seoul 121742, South Korea
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 38期
关键词：
fullerenes; anhydrides; pyrolysis; phthalates;
D O I：
10.1016/j.tetlet.2008.07.064
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Soluble phthalic anhydride-functionalized fullerene was generated via simple pyrolysis of the corresponding di-t-butyl phthalate precursor at 200 degrees C for 120 min. This non-chemical method for generating electrophilic fullerene may be advantageous for the preparation of various fullerene-containing materials. The utility of the resulting fullerene anhydride was demonstrated by solution coupling reaction with PEG-amine, surface reaction with amine-functionalized glass, and hydrolysis reaction to form amphiphilic fullerene. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5540 / 5543
页数：4
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