Green and expeditious synthesis of 1,8-dioxodecahydroacridine derivatives catalysed by protic pyridinium ionic liquid

被引：21

作者：

Alinezhad, Heshmatollah ^{[1
]}

Tajbakhsh, Mahmood ^{[1
]}

Norouzi, Mohammad ^{[1
,2
]}

Baghery, Saeed ^{[3
,4
]}

Rakhtshah, Jamshid ^{[3
]}

机构：

[1] Mazandaran Univ, Dept Chem, Babol Sar, Iran

[2] Payame Noor Univ, Dept Chem, Tehran, Iran

[3] Bu Ali Sina Univ, Coll Sci, Dept Chem, Hamadan, Iran

[4] Islamic Azad Univ, Sci & Res Ayatollah Amoli Branch, Young Researchers Club, Amol, Iran

来源：

JOURNAL OF CHEMICAL SCIENCES | 2013年 / 125卷 / 06期

关键词：

2-Methylpyridinium trifluoromethanesulphonate; Hantzsch three-component condensation; protic ionic liquid; 1,8-dioxodecahydroacridine; water solvent; ACRIDINE-DERIVATIVES; EFFICIENT SYNTHESIS; 1,8-DIOXO-OCTAHYDROXANTHENES; 1,8-DIOXO-DECAHYDROACRIDINES; 9-ARYLPOLYHYDROACRIDINE;

D O I：

10.1007/s12039-013-0517-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Hantzsch three-component condensation reaction of various aromatic aldehydes, 1,3-dione and aniline derivatives in the presence of 2-methylpyridinium trifluoromethanesulphonate ([2-MPyH]OTf) as green and highly efficient catalysts in water affords 1,8-dioxodecahydroacridine derivatives in good to excellent yields. This reaction has been carried out in the presence of 1 mol% of [2-MPyH]OTf at room temperature. The described novel synthesis method proposes several advantages of mild condition, short reaction times, high yields, simplicity and easy work-up compared to the traditional method of synthesis.

引用

页码：1517 / 1522

页数：6

共 37 条

[1]

BAKIBAEV AA, 1991, ZH ORG KHIM+, V27, P1519

[2] Synthesis of Ag and Au nanostructures in an ionic liquid: thermodynamic and kinetic effects underlying nanoparticle, cluster and nanowire formation [J].