Mixed Valency at the Nearly Delocalized Limit: Fundamentals and Forecast

被引：39
作者：
Glover, Starla D. [1 ]
Goeltz, John C. [1 ]
Lear, Benjamin J. [1 ]
Kubiak, Clifford P. [1 ]
机构：
[1] Univ Calif San Diego, La Jolla, CA 92093 USA
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 05期
基金：
美国国家科学基金会;
关键词：
Mixed-valent compounds; Electron transfer; Spectroelectrochemistry; Self-assembly; Ruthenium; SELF-ASSEMBLED MONOLAYERS; INTRAMOLECULAR ELECTRON-TRANSFER; TRINUCLEAR RUTHENIUM CLUSTERS; SOLVENT DYNAMICAL CONTROL; MOLECULAR QCA CELLS; CHARGE-TRANSFER; CYTOCHROME-C; CHEMISTRY; SURFACE; COMPLEXES;
D O I：
10.1002/e.jic.200800910
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Mixed valency is important in many areas of chemistry, from synthetic to biological systems, from the simplest systems to the most highly complex. The purpose of our research is to understand the principles of mixed valency in localized, nearly delocalized, and delocalized systems, and to apply our knowledge to the rational design Of Molecular devices. This microreview discusses our group's research over the last ten years. It reviews methods of estimating picosecond electron-transfer lifetimes from infrared spectral lineshapes, studies of the locatized-to-delocalized transition and the effects of frozen solvents, charge gating by non-covalent interactions, electron-transfer-gated electron transfer, and the distribution of charge within a molecule probed and controlled by all applied electric field. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weirtheim, Germany, 2009)
引用
收藏
页码：585 / 594
页数：10
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