Intercalation of luminescent Europium(III) complexes in layered double hydroxides

被引：32
|
作者：
Sarakha, L.
Forano, C.
Boutinaud, P. [1 ]
机构：
[1] Univ Clermont Ferrand, UMR CNRS 6002, Lab Mat Inorgan, F-63177 Aubiere, France
来源：
OPTICAL MATERIALS | 2009年 / 31卷 / 03期
关键词：
Eu(III) complex; LDH; Photoluminescence; Organic-inorganic hybrid; CLAY-MODIFIED ELECTRODES; OPTICAL-PROPERTIES; CRYSTAL; PARAMETERS; SILICA; ACID;
D O I：
10.1016/j.optmat.2007.10.018
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Anionic Europium(III) complexes EuL1, EuL2 and EuL3 (L1 = tris (dipicolinate), L2 = diethylenetriaminepentaacetate, L3 = disulfonated bathophenanthroline tris(dibenzoylmethanate) were intercalated in Zn2Al(OH)(6)Cl, nH(2)O and Zn4Al(OH)(10)Cl, nH(2)O layered double hydroxides (LDHs). Intercalation was confirmed by X-ray diffraction, vibration spectroscopy and photoluminescence measurements, using Eu(III) as a local structural probe. Information on host-guest interactions in the hybrid materials were deduced by analyzing the intensity parameter Omega(2), the energy position of the D-5(0)-F-7(0) transition and the emission decay profile of the prominent hypersensitive red D-5(0)-F-7(2) emission. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：562 / 566
页数：5
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