Examination of acid-base properties of alumina treated with silane coupling agents, by using inverse gas chromatography

This study examined the specific component of the free energy of adsorption, -Delta G(A)(SP) of the untreated and four types of silane coupling agent-treated alumina powders using inverse gas chromatography (IGC) by employing the adsorption of several polar and non-polar probes onto their surfaces at various temperatures. The acid-base properties of the untreated and surface-treated alumina powders were quantified using their K-A and K-D parameters, which reflect the ability of a surface to act as an electron acceptor and donor, respectively. The surface of the untreated alumina was found to be amphoteric and was able to function as both an electron acceptor and donor. The acid-base properties of the alumina surfaces treated with gamma-glycidoxy propyl trimethoxy silane (GMS) and gamma-amino propyl triethoxy silane (AES) were slightly basic, and those of the alumina surfaces treated with gamma-methacryloxy propyl trimethoxy silane (MTMS) and gamma-mercapto propyl trimethoxy silane (MCMS) were amphoteric. (c) 2008 Elsevier B.V. All rights reserved.