Chemical and Technical Aspects of Propene Oxide Production via Hydrogen Peroxide (HPPO Process)

被引：227

作者：

Russo, V. ^{[1
]}

Tesser, R. ^{[1
]}

Santacesaria, E. ^{[1
]}

Di Serio, M. ^{[1
]}

机构：

[1] Univ Naples Federico II, Dept Chem Sci, I-80126 Naples, Italy

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2013年 / 52卷 / 03期

关键词：

TITANIUM SILICALITE CATALYST; GAS-PHASE EPOXIDATION; PROPYLENE-OXIDE; NITROUS-OXIDE; TS-1; OXIDATION; SOLVENT; BETA; HYDROPHOBICITY; DEACTIVATION;

D O I：

10.1021/ie3023862

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Propene oxide is a very important chemical whose production technology has changed a lot during the last 30 years. Nowadays, the most promising technology is the HPPO process in which the propene oxide is produced by oxidizing propene with hydrogen peroxide, via titanium silicalite-1 (TS-1) catalysis. Even if this technology has been patented in the early 1980s and some chemical plants are already in production, only few papers have been published until now dealing with the catalytic and kinetic aspects of the process. In this paper, the state of the art of the scientific knowledge and technical aspects related to propene oxide synthesis in the presence of TS-1 catalyst have been reviewed.

引用

页码：1168 / 1178

页数：11

共 114 条

[51]

ISHINO M, 2006, 16 SAUD AR JAP JOINT

[52] Oxidation activity of Ti-beta synthesized by a dry-gel conversion method [J].