Fluorescence modulation in anion sensing by introducing intramolecular H-bonding interactions in host-guest adducts

被引:236
|
作者
Chung, YM
Raman, B
Kim, DS
Ahn, KH
机构
[1] POSTECH, Dept Chem, Pohang 790784, South Korea
[2] POSTECH, Div Mol & Life Sci, Ctr Integrated Mol Syst, Pohang 790784, South Korea
关键词
D O I
10.1039/b510795d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fluorescence signaling in anion binding is modulated from quenching to enhancement by intramolecular H-bonding stabilization of anion-ionophore adducts; the intramolecular H-bonding is suggested to suppress the quenching processes otherwise possible and increase the conformational rigidity of the anionic adducts, leading to fluorescence enhancement in a selective fashion towards cyanide ion, among the various anions examined.
引用
收藏
页码:186 / 188
页数:3
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