Transition metal macrocycles for heterogeneous electrochemical CO2 reduction

被引：109

作者：

Lv, Fang ^{[1
,2
]}

Han, Na ^{[3
]}

Qiu, Yuan ^{[1
,2
]}

Liu, Xijun ^{[1
,2
]}

Luo, Jun ^{[1
,2
]}

Li, Yanguang ^{[3
]}

机构：

[1] Tianjin Univ Technol, Sch Mat Sci & Engn, Ctr Electron Microscopy, Tianjin 300384, Peoples R China

[2] Tianjin Univ Technol, Sch Mat Sci & Engn, Tianjin Key Lab Adv Funct Porous Mat, Inst New Energy Mat & Low Carbon Technol, Tianjin 300384, Peoples R China

[3] Soochow Univ, Inst Funct Nano Soft Mat FUNSOM, Jiangsu Key Lab Carbon Based Funct Mat & Devices, Suzhou 215123, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2020年 / 422卷

基金：

中国国家自然科学基金;

关键词：

Transition metal macrocycles; Electrochemical CO2 reduction; Phthalocyanines; Porphyrins; FUNCTIONALIZED CARBON NANOTUBES; COVALENT ORGANIC FRAMEWORKS; COBALT PHTHALOCYANINE; ELECTROCATALYTIC REDUCTION; ELECTROREDUCTION; DIOXIDE; CONVERSION; COMPLEXES; PORPHYRIN; SELECTIVITY;

D O I：

10.1016/j.ccr.2020.213435

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrochemical CO2 reduction reaction (CO2RR) represents a promising approach for converting CO2 to valuable chemical fuels and feedstocks, but its commercial viability is largely hindered by the lack of high-performance electrocatalyst materials. Among a number of candidates, transition metal macrocycles including phthalocyanines and porphyrins have attracted revived attention for their great potentials and structural/functional diversities. Here, we overview recent research advances on these macrocyclic materials for heterogeneous electrochemical CO2RR. It starts with a brief introduction about CO2RR fundamentals and current understanding of the reaction mechanism on transition metal macrocycles. Different strategies are then detailed with examples to show how to optimize their electrocatalytic performances. At the end, we summarize existing scientific challenges and analyze future prospects of this exciting field. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：12

共 91 条

[1] Factors affecting selective electrocatalytic CO2 reduction with cobalt phthalocyanine incorporated in a polyvinylpyridine membrane coated on a graphite electrode [J].