The preparation of mesoporous SnO2 nanotubes by carbon nanofibers template and their lithium storage properties

被引:49
作者
Zhang, Xue [1 ,2 ]
Liang, Jin [1 ,2 ]
Gao, Guoxin [1 ,2 ]
Ding, Shujiang [1 ,2 ]
Yang, Zhenglong [3 ]
Yu, Wei [4 ]
Li, Ben Q. [4 ,5 ]
机构
[1] Xi An Jiao Tong Univ, MOE Key Lab Nonequilibrium Synth & Modulat Conden, Xian 710049, Peoples R China
[2] Xi An Jiao Tong Univ, Sch Sci, Dept Appl Chem, Xian 710049, Peoples R China
[3] Ludong Univ, Sch Chem & Mat Sci, Yantai 264025, Peoples R China
[4] Xi An Jiao Tong Univ, Sch Mech Engn, Xian 710049, Peoples R China
[5] Univ Michigan, Dept Mech Engn, Dearborn, MI 48128 USA
基金
中国国家自然科学基金;
关键词
SnO2; Mesoporous; Nanotubes; Lithium-ion battery; HOLLOW NANOSPHERES; ANODE MATERIALS; FABRICATION; OXIDE; NANOPARTICLES; TRANSPORT; CELLULOSE; SPHERES;
D O I
10.1016/j.electacta.2013.03.036
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mesoporous SnO2 nanotubes are prepared by templating against carbon fibers through a facile solution approach followed by calcination at 800 degrees C for 2 h. The nanotubes are characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA) and nitrogen adsorption. The electrochemical performances as the anodes of lithium-ions batteries are studied by the cyclic voltammogram (CV) and galvanostatic discharge-charge voltage tests. Because of its unique structure (the mesoporous wall, internal void and open ends), the as-obtained mesoporous SnO2 nanotubes demonstrate a reversible capacity of 585 mA h g(-1) up to 50 cycles at a high current density of 400 mAg(-1). (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:263 / 267
页数:5
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