A Tunable Bimetallic MOF-74 for Adsorption Chiller Applications

被引：53

作者：

Liu, Jian ^{[1
]}

Zheng, Jian ^{[1
]}

Barpaga, Dushyant ^{[1
]}

Sabale, Sandip ^{[1
,2
]}

Arey, Bruce ^{[3
]}

Derewinski, Miroslaw A. ^{[1
]}

McGrail, B. Peter ^{[1
]}

Motkuri, Radha Kishan ^{[1
]}

机构：

[1] Pacific Northwest Natl Lab, Richland, WA 99352 USA

[2] Jaysingpur Coll, PG Dept Chem, Jaysingpur 416101, Maharashtra, India

[3] Pacific Northwest Natl Lab, EMSL, Richland, WA 99352 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2018年 / 07期

关键词：

Metal-organic frameworks; Mixed-metal strategy; Adsorption; Nickel; Zinc; METAL-ORGANIC FRAMEWORKS; CARBON-DIOXIDE ADSORPTION; WATER; NI; SEPARATION; DYNAMICS; SORPTION; CAPTURE; ROUTE; SITES;

D O I：

10.1002/ejic.201800042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed-metal strategy, by which a MOF framework with two different metal nodes was prepared, was utilized with MOF-74 for potential adsorption chiller applications. The Ni salt precursor was partially replaced during synthesis with the relatively inexpensive Zn salt. The bimetallic MOF-74 containing only a fraction of Ni was shown to provide efficient H2O adsorption performance, while utilizing the more inexpensive Zn salt thus significantly mitigated the material costs of industrial scale synthesis/applications.

引用

收藏

页码：885 / 889

页数：5

相关论文

共 37 条

[1] The effect of pyridine modification of Ni-DOBDC on CO2 capture under humid conditions [J].

Bae, Youn-Sang ;

Liu, Jian ;

Wilmer, Christopher E. ;

Sun, Hahnbi ;

Dickey, Allison N. ;

Kim, Min Bum ;

Benin, Annabelle I. ;

Willis, Richard R. ;

Barpaga, Dushyant ;

LeVan, M. Douglas ;

Snurr, Randall Q. .

CHEMICAL COMMUNICATIONS, 2014, 50 (25) :3296-3298

[2] Highly efficient separation of carbon dioxide by a metal-organic framework replete with open metal sites [J].

Britt, David ;

Furukawa, Hiroyasu ;

Wang, Bo ;

Glover, T. Grant ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (49) :20637-20640

[3] A water-based and high space-time yield synthetic route to MOF Ni2(dhtp) and its linker 2,5-dihydroxyterephthalic acid [J].

Cadot, Stephane ;

Veyre, Laurent ;

Luneau, Dominique ;

Farrusseng, David ;

Quadrelli, Elsje Alessandra .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (42) :17757-17763

[4] Dramatic tuning of carbon dioxide uptake via metal substitution in a coordination polymer with cylindrical pores [J].

Caskey, Stephen R. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) :10870-+

[5] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[6] Evaluation of an industrial pilot scale densified MOF-177 adsorbent as an on-board hydrogen storage medium [J].

Dailly, Anne ;

Poirier, Eric .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3527-3534

[7] An Efficient Synthesis Strategy for Metal-Organic Frameworks: Dry-Gel Synthesis of MOF-74 Framework with High Yield and Improved Performance [J].

Das, Atanu Kumar ;

Vemuri, Rama Sesha ;

Kutnyakov, Igor ;

McGrail, B. Peter ;

Motkuri, Radha Kishan .

SCIENTIFIC REPORTS, 2016, 6

[8] Metal-Organic Frameworks - Heading towards Application [J].

Dietzel, Pascal D. C. ;

Kitagawa, Hiroshi .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2016, (27) :4273-4274

[9] Synthesis, Characterization, and Application of Metal Organic Framework Nanostructures [J].

Fernandez, Carlos A. ;

Nune, Satish K. ;

Motkuri, Radha Kishan ;

Thallapally, Praveen K. ;

Wang, Chongmin ;

Liu, Jun ;

Exarhos, Gregory J. ;

McGrail, B. Peter .

LANGMUIR, 2010, 26 (24) :18591-18594

[10]

Furukawa H., 2015, ANGEW CHEM, V127, P3480

← 1 2 3 4 →