15N NMR Studies of tautomerism

被引：22

作者：

Kolehmainen, Erkki ^{[1
]}

Osmialowski, Borys ^{[2
]}

机构：

[1] Univ Jyvaskyla, Dept Chem, FI-40014 Jyvaskyla, Finland

[2] Univ Technol & Life Sci, Fac Chem Technol & Engn, PL-85326 Bydgoszcz, Poland

来源：

INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY | 2012年 / 31卷 / 04期

关键词：

15N NMR; tautomerism; solid-state NMR; liquid state NMR; calculations; SOLID-STATE NMR; NUCLEAR-MAGNETIC-RESONANCE; DOUBLE-PROTON-TRANSFER; PI-ELECTRON DELOCALIZATION; MOLECULAR-ORBITAL METHODS; BARRIER HYDROGEN-BONDS; X-RAY CRYSTALLOGRAPHY; N-15; NMR; CHEMICAL-SHIFT; AB-INITIO;

D O I：

10.1080/0144235X.2012.734157

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The literature related to 15N NMR studies of tautomerism is updated and discussed. The 15N NMR data show that the technique is applicable for both liquid and solid state (both crystalline and amorphous) materials. Modern computational methods combined with experimental NMR data can aid in the chemical shift assignments especially in case of crystalline materials (so-called NMR crystallography). This review article is divided into chapters based on the different classes of compounds and a brief description of experimental and computational NMR techniques is also included.

引用

页码：567 / 629

页数：63

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