Microwave synthesized nanostructured TiO2-activated carbon composite electrodes for supercapacitor

被引:90
作者
Selvakumar, M. [1 ]
Bhat, D. Krishna [2 ]
机构
[1] Manipal Inst Technol, Dept Chem, Manipal 576104, Karnataka, India
[2] Natl Inst Technol Karnataka Surathkal, Dept Chem, Srinivasnagar 575025, India
关键词
Titanium oxide; Microwave synthesis; Activated carbon; Supercapacitor; Galvanostatic charge-discharge; OXIDE; NANOTUBES; FILMS;
D O I
10.1016/j.apsusc.2012.09.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Electrochemical properties of a supercapacitor based on nanocomposite electrodes of activated carbon with TiO2 nano particles synthesized by a microwave method have been determined. The TiO2/activated carbon nanocomposite electrode with a composition of 1:3 showed a specific capacitance 92 Fg(-1). The specific capacitance of the electrode decreased with increase in titanium dioxide content. The p/p symmetrical supercapacitor fabricated with TiO2/activated carbon composite electrodes showed a specific capacitance of 122 Fg(-1). The electrochemical behavior of the neat TiO2 nanoparticles has also been studied for comparison purpose. The galvanostatic charge-discharge test of the fabricated supercapacitor showed that the device has good coulombic efficiency and cycle life. The specific capacitance of the supercapacitor was stable up to 5000 cycles at current densities of 2, 4, 6 and 7 mAcm(-2). (C) 2012 Elsevier B. V. All rights reserved.
引用
收藏
页码:236 / 241
页数:6
相关论文
共 30 条
  • [1] Optimization of MnO2/vertically aligned carbon nanotube composite for supercapacitor application
    Amade, Roger
    Jover, Eric
    Caglar, Burak
    Mutlu, Toygan
    Bertran, Enric
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (13) : 5779 - 5783
  • [2] Enhanced supercapacitance of multiwalled carbon nanotubes functionalized with ruthenium oxide
    Arabale, G
    Wagh, D
    Kulkarni, M
    Mulla, IS
    Vernekar, SP
    Vijayamohanan, K
    Rao, AM
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 376 (1-2) : 207 - 213
  • [3] TRANSITION FROM SUPERCAPACITOR TO BATTERY BEHAVIOR IN ELECTROCHEMICAL ENERGY-STORAGE
    CONWAY, BE
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (06) : 1539 - 1548
  • [4] Microwave chemistry
    Galema, SA
    [J]. CHEMICAL SOCIETY REVIEWS, 1997, 26 (03) : 233 - 238
  • [5] TiO2 nanotubes:: H+ insertion and strong electrochromic effects
    Ghicov, A
    Tsuchiya, H
    Hahn, R
    Macak, JM
    Muñoz, AG
    Schmuki, P
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (04) : 528 - 532
  • [6] Effects of substrates on the capacitive performance of RuOx•nH2O and activated carbon-RuOx electrodes for supercapacitors
    Hu, CC
    Chen, WC
    [J]. ELECTROCHIMICA ACTA, 2004, 49 (21) : 3469 - 3477
  • [7] Rotating ring-disk studies of oxidized nickel hydrous oxide: oxygen evolution and pseudocapacitance
    Hu, YN
    Tolmachev, YV
    Scherson, DA
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 468 (01): : 64 - 69
  • [8] Synthesis and characterization of tin oxide/carbon aerogel composite electrodes for electrochemical supercapacitors
    Hwang, Sung-Woo
    Hyun, Sang-Hoon
    [J]. JOURNAL OF POWER SOURCES, 2007, 172 (01) : 451 - 459
  • [9] ELECTRIC DOUBLE-LAYER CAPACITOR COMPOSED OF ACTIVATED CARBON-FIBER CLOTH ELECTRODES AND SOLID POLYMER ELECTROLYTES CONTAINING ALKYLAMMONIUM SALTS
    ISHIKAWA, M
    MORITA, M
    IHARA, M
    MATSUDA, Y
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) : 1730 - 1734
  • [10] Jayalakshmi M, 2008, INT J ELECTROCHEM SC, V3, P96