Mechanochemical synthesis of isoreticular metal-organic frameworks and comparative study of their potential for nitrobenzene sensing

被引：38

作者：

Abedi, Sedigheh ^{[1
]}

Tehrani, Alireza Azhdari ^{[1
]}

Morsali, Ali ^{[1
]}

机构：

[1] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran, Iran

来源：

NEW JOURNAL OF CHEMISTRY | 2015年 / 39卷 / 07期

基金：

美国国家科学基金会;

关键词：

ADSORPTION; FUNCTIONALIZATION;

D O I：

10.1039/c5nj00153f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of halogen containing isoreticular metal-organic frameworks (IRMOFs) were synthesized via a liquid-assisted grinding method. The luminescence properties of these frameworks were described for nitrobenzene sensing. This investigation revealed the prominent roles of frontier molecular orbital energies of the linkers, substitution polarizability and structural parameters in the ability of IRMOFs to sense nitrobenzene.

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收藏

页码：5108 / 5111

页数：4

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