Evidence of macro-micro domain transition in poled PMN-PZT ceramics

被引:19
作者
Du, Gang [1 ]
Liang, Ruihong [1 ]
Wang, Junxia [1 ]
Wang, Li [1 ]
Zhang, Wenbin [1 ]
Wang, Genshui [1 ]
Dong, Xianlin [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 201800, Peoples R China
关键词
Microdomain; Macrodomain; Piezoelectric ceramics; Relaxor; RELAXOR FERROELECTRIC TRANSFORMATIONS; PHASE-TRANSITION; BEHAVIOR; FIELD;
D O I
10.1016/j.ceramint.2013.05.044
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The dielectric properties of unpoled and poled Pb0.88Ba0.06Sr0.06(Mg1/3Nb2/3)(0.37)Zr0.375Ti0.255O3 (modified PMN-PZT) ceramics were investigated. It was found that the dielectric constant increased while the loss tangent decreased after poling. A frequency independent abrupt transition in the dielectric constant and loss tangent responses was observed for the poled ceramics. This abnormal behavior was believed to be correlated with the macro-micro domain transition and the corresponding pyroelectric measurement exhibited a narrow peak at the normal-relaxor transition temperature T-nr. Furthermore, the presence of double-loop-like hysteresis and two types of current peaks at a temperature slightly higher than T-nr showed another strong evidence of this transition. (C) 2013 Elsevier Ltd and Techna Group S.r.l. All tights reserved.
引用
收藏
页码:9299 / 9303
页数:5
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