Chiral Ruthenium(II) Complexes as Supramolecular Building Blocks for Heterometallic Self-Assembly

被引：20

作者：

Iranmanesh, Hasti ^{[1
]}

Arachchige, Kasun S. A. ^{[1
,6
]}

Bhadbhade, Mohan ^{[2
]}

Donald, William A. ^{[1
]}

Liew, Jane Y. ^{[3
]}

Liu, Kenny T. -C. ^{[1
]}

Luis, Ena T. ^{[1
]}

Moore, Evan G. ^{[3
]}

Price, Jason R. ^{[4
]}

Yan, Hong ^{[5
]}

Yang, Jiajia ^{[1
,5
]}

Beves, Jonathon E. ^{[1
,5
]}

机构：

[1] UNSW Australia, Sch Chem, Sydney, NSW, Australia

[2] UNSW Australia, Mark Wainwright Analyt Ctr, Sydney, NSW, Australia

[3] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld, Australia

[4] Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia

[5] Nanjing Univ, Key State Lab Coordinat Chem, Nanjing, Jiangsu, Peoples R China

[6] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld, Australia

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 24期

基金：

澳大利亚研究理事会; 美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; LIGHT PHOTOREDOX CATALYSIS; ENERGY-TRANSFER; METALLOLIGAND STRATEGY; HYDROGEN-PRODUCTION; MERGING PHOTOREDOX; RU COMPLEX; CAGES; FUNCTIONALIZATION; CONSTRUCTION;

D O I：

10.1021/acs.inorgchem.6b02007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of enantiopure ruthenium(II) polypyridyl complexes are reported that feature pendant pyridyl groups suitable for building larger self-assembled structures. The complexes are characterized in detail in solution using NMR spectroscopy, cyclic voltammetry, and photophysical methods and in the solid state using single-crystal X-ray crystallography. The complexes are luminescent, displaying long excited-state lifetimes that are quenched when the pendant pyridyl groups are protonated. Reaction with cadmium(II) ions results in the formation of a mixed-metal one-dimensional coordination polymer, crystallography. which was characterized by single-crystal X-ray crystallography.

引用

页码：12737 / 12751

页数：15

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