Thermal characterizations of the graphite nanosheets reinforced paraffin phase-change composites

被引:64
作者
Chen, Yin-Ju [1 ]
Duc-Dung Nguyen [1 ]
Shen, Ming-Yuan [2 ,3 ]
Yip, Ming-Chuen [2 ]
Tai, Nyan-Hwa [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan
[2] Natl Tsing Hua Univ, Dept Power Mech Engn, Hsinchu 30013, Taiwan
[3] Plast Ind Dev Ctr, Taichung 401, Taiwan
关键词
Polymer-matrix composites (PMCs); Thermal properties; Thermal analysis; CHANGE ENERGY-STORAGE; CONDUCTIVITY; MATRIX;
D O I
10.1016/j.compositesa.2012.08.010
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Two paraffin composites filled separately with randomly distributed graphite nanosheets (R-GNs) and oriented graphite nanosheets (O-GNs) were fabricated, and their thermal properties and structural characteristics were investigated. The experimental results show that a conductive network at 1.0 wt.% graphite nanosheet (GN) loading was found. The thermal conductivities of the R-GNs/paraffin and the O-GNs/paraffin composites are 4.47 +/- 0.15 and 1.68 +/- 0.07 W/m K, respectively, when 5.0 wt.% GNs were introduced. The Maxwell-Euken model and the modified rule of mixtures model were proposed to predict the thermal conductivities of the R-GNs/paraffin and the O-GNs/paraffin composites, respectively. The melting point and the solid-liquid phase transition temperature of the R-GNs/paraffin composites are approximately 53 and 60 degrees C, respectively, and neither of these values was significantly affected by the presence of GNs. Decreases in the latent heat of the R-GNs/paraffin composites with increased GN loading were also found. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:40 / 46
页数:7
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