Design and synthesis by redox polymerization of a bio-based carboxylic elastomer for green tire

被引：19

作者：

Zhou, Xinxin ^{[1
,2
]}

Wang, Runguo ^{[1
,2
]}

Lei, Weiwei ^{[1
,2
]}

Qiao, He ^{[1
,2
]}

Ji, Haoling ^{[2
]}

Zhang, Liqun ^{[1
,2
,3
]}

Hua, Kuo-Chih ^{[4
]}

Kulig, Joseph ^{[4
]}

机构：

[1] Beijing Univ Chem Technol, State Key Lab Organ Inorgan Composites, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Key Lab Beijing City Preparat & Proc Novel Polyme, Beijing 100029, Peoples R China

[3] Beijing Univ Chem Technol, Beijing Lab Biomed Mat, Beijing 100029, Peoples R China

[4] Goodyear Tire & Rubber Co, Goodyear Innovat Ctr, Akron, OH 44316 USA

来源：

SCIENCE CHINA-CHEMISTRY | 2015年 / 58卷 / 10期

基金：

中国国家自然科学基金;

关键词：

carboxylic rubber; bio-based elastomer; synthesis; redox polymerozation; green tire; MECHANICAL-PROPERTIES; NATURAL-RUBBER; BUTADIENE; ACID; FILLER; SILICA; NANOCOMPOSITES; BUTANOL;

D O I：

10.1007/s11426-015-5332-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(dibutyl itaconate-co-isoprene-co-methacrylic acid) (PDIM) elastomer was designed and synthesized by redox emulsion polymerization under mild conditions. PDIM has high molecular weight, relatively high yield, and low glass transition temperature (T (g)). The structure of PDIM was determined by FTIR and NMR, and the carboxyl content was obtained by titration in a non-proton solvent. Tensile strength and elongation at break increased with increasing carboxyl content. In addition, the interaction between PDIM and silica was elucidated by rubber process analyzer (RPA) and TEM, and the results showed that the silica-PDIM interaction was strong, but the silica-silica interaction was weak.

引用

页码：1561 / 1569

页数：9

共 36 条

[1] Effect of carboxylic acid monomer and butadiene on particle growth in the emulsifier-free emulsion copolymerization of styrene-butadiene-carboxylic acid monomer [J].

Abdollahi, Mahdi ;

Sharifpour, Maryam .

POLYMER, 2007, 48 (07) :2035-2045

[2]

[Anonymous], TRANSPORT

[3]

[Anonymous], NMR CHEM BIOL

[4] Polyreactions in miniemulsions [J].

Antonietti, M ;

Landfester, K .

PROGRESS IN POLYMER SCIENCE, 2002, 27 (04) :689-757

[5] Studies on Novel Dual Filler Based Epoxidized Natural Rubber Nanocomposite [J].

Chattopadhyay, Pijush Kanti ;

Basuli, Utpal ;

Chattopadhyay, Santanu .

POLYMER COMPOSITES, 2010, 31 (05) :835-846

[6] Carboxylated butadiene-styrene rubber/halloysite nanotube nanocomposites: Interfacial interaction and performance [J].

Du, Mingliang ;

Guo, Baochun ;

Lei, Yanda ;

Liu, Mingxian ;

Jia, Demin .

POLYMER, 2008, 49 (22) :4871-4876

[7] The effect of filler-filler and filler-elastomer interaction on rubber reinforcement [J].

Fröhlich, J ;

Niedermeier, W ;

Luginsland, HD .

COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2005, 36 (04) :449-460

[8]

Ghosh S, 2011, TIRE SCI TECHNOL, V39, P210, DOI 10.2346/1.3637744

[9] Fermentative production of butanol - the industrial perspective [J].

Green, Edward M. .

CURRENT OPINION IN BIOTECHNOLOGY, 2011, 22 (03) :337-343

[10] Fundamentals of rolling resistance [J].

Hall, DE ;

Moreland, JC .

RUBBER CHEMISTRY AND TECHNOLOGY, 2001, 74 (03) :525-539

← 1 2 3 4 →