Cd(II) complexes based on a tricarboxylate: synthesis, structural characterization and properties

被引：2

作者：

Kuai, Hai-Wei ^{[1
]}

Cheng, Xiao-Chun ^{[1
]}

Zhu, Xiao-Hong ^{[1
]}

机构：

[1] Huaiyin Inst Technol, Fac Life Sci & Chem Engn, Huaian, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2013年 / 66卷 / 17期

关键词：

Cd(II) complexes; Structural characterization; Fluorescence; Adsorption; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; ZINC(II); IMIDAZOLE; LIGANDS;

D O I：

10.1080/00958972.2013.821199

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of cadmium(II) with 5-(4-carboxybenzylamino)isophthalic acid (H3L) in the presence of 2-(pyridin-2-yl)-1H-benzo[d]imidazole (pybim) and 2,2'-bipyridine (bpy) by hydrothermal method lead to two complexes, [Cd(HL)(pybim)]center dot H2O (1) and [Cd-2(L)(HCOO)(bpy)(2)(H2O)]center dot H2O (2). Complexes 1 and 2 have been characterized by single-crystal and powder X-ray diffraction, Infrared spectra, and elemental and thermogravimetric analyses. 1 has a double-chain structure while 2 consists of uninodal 3-connected 2-D hcb networks with (6(3)) topology. Luminescence and sorption properties of 1 and 2 were also investigated.

引用

页码：2970 / 2979

页数：10

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