New clay-reinforced polyamide nanocomposite based on 4-phenylenediacrylic acid: Synthesis and properties

New type of aromatic polyamide/montmorillonite nanocomposites were produced using solution intercalation technique in N-methyl-2-pyrrolidone. High-molecular-weight amide chains were synthesized from 4,4'-diaminodiphenyl ether and 4-phenylenediacrylic acid in N-methyl-2-pyrrolidone. The resulting nanocomposite films containing 5-20 wt.% of organoclay (Cloisite (R) 20A) were characterized for FT-IR, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), optical transparency and water absorption measurements. The distribution of organoclay and nanostructure of the composites were investigated by (XRD) and SEM analyses. Thermogravimetric analysis indicated an increase in thermal stability of nanocomposites as compared to pristine polyamide. The percentage optical transparency and water absorption of these hybrids was found to be much reduced upon the addition of modified layered silicate indicating decreased permeability. (c) 2011 King Saud University. Production and hosting by Elsevier B.V. All rights reserved.