Thermodynamic parameters of adsorption of isomeric chloronaphthalenes on graphitized thermal carbon black

被引：2

作者：

Buryak, AK ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Phys Chem, Moscow 117915, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 08期

关键词：

chloronaphthalenes; ortho-effect; semi-empirical molecular statistical calculations; heats of adsorption; Henry's constants;

D O I：

10.1007/BF02496393

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Henry's constants and the heats of adsorption of isomeric chloronaphthalenes on graphitized thermal carbon black were calculated by the semiempirical molecular statistical method. The calculated data were compared with experimental results. The best agreement was achieved when corrections for the interaction of the Cn atom with the C atom of the adjacent benzene ring and the presence of other Cl atoms in ortho-positions are introduced in calculations of the atom-atomic potentials.

引用

页码：1467 / 1471

页数：5

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