Dynamic Single Crystals: Kinematic Analysis of Photoinduced Crystal Jumping (The Photosalient Effect)

被引：251

作者：

Naumov, Pance ^{[1
]}

Sahoo, Subash Chandra ^{[1
]}

Zakharov, Boris A. ^{[2
,3
]}

Boldyreva, Elena V. ^{[2
,3
]}

机构：

[1] New York Univ Abu Dhabi, Abu Dhabi, U Arab Emirates

[2] Russian Acad Sci, Inst Solid State Chem & Mechanochem, Siberian Branch, Novosibirsk 630128, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期

关键词：

actuators; biomimetic materials; isomers; jumping crystals; mechanical effects; PHOTOACTIVE YELLOW PROTEIN; SOLID-STATE; LINKAGE ISOMERIZATION; PHASE-TRANSITION; (+/-)-3,4-DI-O-ACETYL-1,2,5,6-TETRA-O-BENZYL-MYO-INOSITOL; CHEMISTRY;

D O I：

10.1002/anie.201303757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystals on the move: If they are subjected to a strong light stimulus, crystals of the cobalt coordination compound [Co(NH3) 5(NO2)]Cl(NO3) undergo sudden jumps and leap over distances 102-105 times their own size to release the strain that accumulates in their interior. The first quantitative kinematic analysis of this phenomenon is reported. The observed effect could be employed for actuation on the macroscopic scale. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9990 / 9995

页数：6

共 45 条

[1] DIE GESCHWINDIGKEIT DER RUCKWANDLUNG VON BESTRAHLTEM FESTEM NITROPENTAMMINKOBALT(III)-CHLORID [J].