Effect of the Structural Characteristics of Binary Pt-Ru and Ternary Pt-Ru-M Fuel Cell Catalysts on the Activity of Ethanol Electrooxidation in Acid Medium

被引:40
作者
Antolini, Ermete [1 ]
机构
[1] Scuola Sci Mat, I-16016 Genoa, Italy
关键词
electrochemistry; ethanol oxidation; fuel cells; platinum; ruthenium; SITU FTIR SPECTROSCOPY; OXIDATION; ELECTROCATALYSTS; PLATINUM; METHANOL; PTRU/C; REDUCTION; ELECTRODES; ANODE; NANOPARTICLES;
D O I
10.1002/cssc.201300138
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In view of their possible use as anode materials in acid direct ethanol fuel cells, the electrocatalytic activity of Pt-Ru and Pt-Ru-M catalysts for ethanol oxidation has been investigated. This minireview examines the effects of the structural characteristics of Pt-Ru, such as the degree of alloying and Ru oxidation state, on the electrocatalytic activity for ethanol oxidation.
引用
收藏
页码:966 / 973
页数:8
相关论文
共 63 条
  • [11] METAL CRYSTALLINITY EFFECTS IN ELECTROCATALYSIS AS PROBED BY REAL-TIME FTIR SPECTROSCOPY - ELECTROOXIDATION OF FORMIC-ACID, METHANOL, AND ETHANOL ON ORDERED LOW-INDEX PLATINUM SURFACES
    CHANG, SC
    LEUNG, LWH
    WEAVER, MJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (15) : 6013 - 6021
  • [12] Promotion of PtRu/C anode catalysts for ethanol oxidation reaction by addition of Sn modifier
    Chang, Yu-Wei
    Liu, Chen-Wei
    Wei, Yu-Chen
    Wang, Kuan-Wen
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (11) : 2161 - 2164
  • [13] Electro-oxidation of ethanol and ethylene glycol on carbon-supported nano-Pt and -PtRu catalyst in acid solution
    Chatterjee, Moitrayee
    Chatterjee, Abhik
    Ghosh, Susanta
    Basumallick, I.
    [J]. ELECTROCHIMICA ACTA, 2009, 54 (28) : 7299 - 7304
  • [14] Combinatorial investigation of Pt-Ru-Sn alloys as an anode electrocatalysts for direct alcohol fuel cells
    Chu, Young Hwan
    Shul, Yong Gun
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (20) : 11261 - 11270
  • [15] Ethanol oxidation on novel, carbon supported Pt alloy catalysts - Model studies under defined diffusion conditions
    Colmenares, L.
    Wang, H.
    Jusys, Z.
    Jiang, L.
    Yan, S.
    Sun, G. Q.
    Behm, R. J.
    [J]. ELECTROCHIMICA ACTA, 2006, 52 (01) : 221 - 233
  • [16] Preparation, characterization and application of Pt-Ru-Sn/C trimetallic electrocatalysts for ethanol oxidation in direct fuel cell
    Cunha, E. M.
    Ribeiro, J.
    Kokoh, K. B.
    de Andrade, A. R.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (17) : 11034 - 11042
  • [17] A comprehensive study on the effect of Ru addition to Pt electrodes for direct ethanol fuel cell
    Datta, J.
    Singh, S.
    Das, S.
    Bandyopadhyay, N. R.
    [J]. BULLETIN OF MATERIALS SCIENCE, 2009, 32 (06) : 643 - 652
  • [18] Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes. A study using DEMS and in-situ FTIR techniques
    de Souza, JPI
    Queiroz, SL
    Bergamaski, K
    Gonzalez, ER
    Nart, FC
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (38) : 9825 - 9830
  • [19] Ethanol electrooxidation onto stepped surfaces modified by Ru deposition:: electrochemical and spectroscopic studies
    Del Colle, V.
    Berna, A.
    Tremiliosi-Filho, G.
    Herrero, E.
    Feliu, J. M.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (25) : 3766 - 3773
  • [20] Ethanol oxidation on PtRu electrodes studied by differential electrochemical mass spectrometry
    Fujiwara, N
    Friedrich, KA
    Stimming, U
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 472 (02) : 120 - 125