Compatibilization Mechanism of Nanoclay in Immiscible PS/PMMA Blend Using Unmodified Nanoclay

被引：27

作者：

Iyer, Rajesh ^{[1
]}

Suin, Supratim ^{[1
]}

Shrivastava, Nilesh K. ^{[1
]}

Maiti, Sandip ^{[1
]}

Khatua, B. B. ^{[1
]}

机构：

[1] Indian Inst Technol, Ctr Mat Sci, Kharagpur 721302, W Bengal, India

来源：

POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING | 2013年 / 52卷 / 05期

关键词：

Compatibilizer; Immiscible blend; Nanoclay; PMMA; PS; MODIFIED LAYERED SILICATE; MORPHOLOGY; NANOCOMPOSITES; PLATELETS; INTERFACE; CLAY;

D O I：

10.1080/03602559.2012.762024

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Organically modified nanoclays have been reported to play the role of a compatibilizer for immiscible polymer blends. However, the mechanism of compatibilization by nanoclay has been reported differently. In this work, we investigated the exact mechanism of compatibilization of nanoclay in immiscible polystyrene (PS)/poly(methyl methacrylate) (PMMA) blend in the presence of sodium-montmorillonite (Na-MMT) through selective dispersion of clay in the matrix phase. Through a detailed investigation of the morphology of PS/PMMA/Na-MMT blend nanocomposites, the plausible mechanism behind the compatibilization effect of clay in immiscible blends has been proposed.

引用

页码：514 / 524

页数：11

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