Increased control over the desolvation of p-tert-butylcalix[5]arene

被引：3

作者：

Tian, Jian ^{[1
]}

Dalgarno, Scott J. ^{[1
,2
]}

Thallapally, Praveen K. ^{[1
]}

Atwood, Jerry L. ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA

[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

CRYSTENGCOMM | 2009年 / 11卷 / 01期

关键词：

ORGANIC FRAMEWORKS; GAS SORPTION; HYDROGEN; CRYSTALLINE; STORAGE;

D O I：

10.1039/b813628a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Parital de-solvation of the toluene solvate of p-tert-butylcalix[5]arene affords a frustrated organic solid that is a new type of sorbant. Increased control over this sorption is achieved by employing a high boiling solvent for incremental de-solvation, revealing the calixarene : solvent ratio for maximum gas sorption.

引用

页码：33 / 35

页数：3

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