Increased control over the desolvation of p-tert-butylcalix[5]arene

被引：3
|
作者：
Tian, Jian [1 ]
Dalgarno, Scott J. [1 ,2 ]
Thallapally, Praveen K. [1 ]
Atwood, Jerry L. [1 ]
机构：
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[2] Heriot Watt Univ, Sch Engn & Phys Sci Chem, Edinburgh EH14 4AS, Midlothian, Scotland
来源：
CRYSTENGCOMM | 2009年 / 11卷 / 01期
关键词：
ORGANIC FRAMEWORKS; GAS SORPTION; HYDROGEN; CRYSTALLINE; STORAGE;
D O I：
10.1039/b813628a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Parital de-solvation of the toluene solvate of p-tert-butylcalix[5]arene affords a frustrated organic solid that is a new type of sorbant. Increased control over this sorption is achieved by employing a high boiling solvent for incremental de-solvation, revealing the calixarene : solvent ratio for maximum gas sorption.
引用
收藏
页码：33 / 35
页数：3
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