Palladium-Catalyzed Intermolecular Oxyarylation of Vinylacetates with Retention of an Alkenyl Moiety

被引：7
|
作者：
Qiu, Sheng-Qi [1 ]
Xu, Yun-He [1 ]
Loh, Teck-Peng [1 ,2 ]
机构：
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[2] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
ORGANIC LETTERS | 2015年 / 17卷 / 14期
基金：
美国国家科学基金会; 中国国家自然科学基金;
关键词：
H BOND ACTIVATION; HECK REACTION; METAL-FREE; ASYMMETRIC-SYNTHESIS; EFFICIENT SYNTHESIS; SELECTIVE ACCESS; TERMINAL ALKENES; DIRECT ARYLATION; DERIVATIVES; OLEFINATION;
D O I：
10.1021/acs.orglett.5b01507
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed intermolecular oxyarylation reaction of vinylacetates with retention of the double bond in the final product is developed. Under the optimized reaction conditions, the desired products of multisubstituted vinylesters could be obtained in moderate to high yields.
引用
收藏
页码：3462 / 3465
页数：4
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