A convenient synthesis of (Z)-1-chloro-1-alkenes and (Z)-1-chloro-2-alkoxy-1-alkenes

被引：30
作者：
Baati, R
Barma, DK
Krishna, UM
Mioskowski, C [1 ]
Falck, JR
机构：
[1] Univ Louis Pasteur Strasbourg 1, Fac Pharm, Lab Synth Bioorgan, UMR 7514, F-67401 Illkirch Graffenstaden, France
[2] Univ Texas, SW Med Ctr, Dept Biochem, Dallas, TX 75390 USA
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 06期
基金：
美国国家卫生研究院;
关键词：
alkenyl halides; carbenoids; chromium; enol ethers;
D O I：
10.1016/S0040-4039(01)02304-8
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Mild, room temperature CrCl2 reduction of 1,1,1-trichloroalkanes stereoselectively generates (Z)-1-chloro-2-substituted-1-alkenes in excellent yields. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：959 / 961
页数：3
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