Valence-to-core X-ray emission spectroscopy of Ti, TiO, and TiO2 by means of a double full-cylinder crystal von Hamos spectrometer

被引：13
|
作者：
Wansleben, Malte [1 ]
Vinson, John [2 ]
Holfelder, Ina [1 ]
Kayser, Yves [1 ]
Beckhoff, Burkhard [1 ]
机构：
[1] Phys Tech Bundesanstalt, Abbestr 2-12, D-10587 Berlin, Germany
[2] NIST, Mat Measurement Lab, Gaithersburg, MD 20899 USA
来源：
X-RAY SPECTROMETRY | 2019年 / 48卷 / 02期
关键词：
SPECTRA;
D O I：
10.1002/xrs.3000
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
We present valence-to-core X-ray emission spectroscopy of Ti, TiO, and TiO2 by means of a double crystal von Hamos spectrometer based on full-cylinder highly annealed pyrolytic graphite mosaic crystals. We demonstrate that, using a double crystal configuration, an energy resolution of E/Delta E approximate to 2,700 can be achieved in a compact setup using cylindrically curved optics with a radius of curvature of 50 mm. The stated energy resolution proved to be high enough to identify and determine chemical shifts of the K beta(2,5) and K beta '' emission lines of both oxides. The experimental results are supported by calculations with the ab initio package OCEAN and compared with literature values.
引用
收藏
页码：105 / 109
页数：5
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