Pollutant emissions in a bubbling fluidized bed combustor working in oxy-fuel operating conditions: Effect of flue gas recirculation

被引：68

作者：

de Diego, L. F. ^{[1
]}

de las Obras-Loscertales, M. ^{[1
]}

Rufas, A. ^{[1
]}

Garcia-Labiano, F. ^{[1
]}

Gayan, P. ^{[1
]}

Abad, A. ^{[1
]}

Adanez, J. ^{[1
]}

机构：

[1] Inst Carboquim ICB CSIC, Environm & Energy Dept, Zaragoza 50018, Spain

来源：

APPLIED ENERGY | 2013年 / 102卷

关键词：

Oxy-fuel combustion; Fluidized bed; Pollutant emission; Gas recirculation; NO/N2O CHEMISTRY; COAL COMBUSTION; N2O FORMATION; SO2; NOX; SULFATION; LIMESTONE; STEAM; CHAR;

D O I：

10.1016/j.apenergy.2012.08.053

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

In this work, pollutant emissions in a continuous bubbling fluidized bed combustor (similar to 3 kW(th)) at oxy-firing conditions were measured. An anthracite coal was used as fuel and a limestone was added for sulfur retention. Flue gas recirculation was simulated by mixing different gases (CO2, SO2, steam, and NO) and the effect of varying the gas composition of the recycled flow on the pollutant emissions was analyzed. It was observed that the most important effect of CO2 recirculation was the increase of the optimum temperature for SO2 retention from similar to 850 degrees C (conventional air combustion) to 900-925 degrees C. SO2 recirculation increased the Ca-based sorbent utilization and did not affect the N2O emissions at any temperature. In addition, at 850 degrees C the CO emission increased and the NO emission decreased, however, at 925 degrees C the CO variation was negligible and the NO reduction was low. About 60-70% of the recycled NO was reduced to N-2 and N2O, being the NO converted to N2O lower than 5%. Steam recirculation mainly led to a sharp decrease in NO emission. A synergetic effect among the different recycled gases was not found in any case. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：860 / 867

页数：8

共 30 条

[11] NOx and N2O emission in bubbling fluidized-bed coal combustion with oxygen and recycled flue gas:: Macroscopic characteristics of their formation and reduction [J].

Hosoda, H ;

Hirama, T ;

Azuma, N ;

Kuramoto, K ;

Hayashi, J ;

Chiba, T .

ENERGY & FUELS, 1998, 12 (01) :102-108

[12] Experimental study of oxy-fuel combustion and sulfur capture in a Mini-CFBC [J].

Jia, L. ;

Tan, Y. ;

Wang, C. ;

Anthony, E. J. .

ENERGY & FUELS, 2007, 21 (06) :3160-3164

[13] Commissioning of a 0.8 MWth CFBC for oxy-fuel combustion [J].

Jia, L. ;

Tan, Y. ;

McCalden, D. ;

Wu, Y. ;

He, I. ;

Symonds, R. ;

Anthony, E. J. .

INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2012, 7 :240-243

[14] Emissions of SO2 and NOx during Oxy-Fuel CFB Combustion Tests in a Mini-Circulating Fluidized Bed Combustion Reactor [J].

Jia, L. ;

Tan, Y. ;

Anthony, E. J. .

ENERGY & FUELS, 2010, 24 (02) :910-915

[15]

Johnsson J., 1991, Proceedings 11th International Conference on Fluidised Bed Combustion, P1389

[16] HOMOGENEOUS N2O CHEMISTRY AT FLUIDIZED-BED COMBUSTION CONDITIONS - A KINETIC MODELING STUDY [J].

KILPINEN, P ;

HUPA, M .

COMBUSTION AND FLAME, 1991, 85 (1-2) :94-104

[17] MECHANISMS OF NITROUS-OXIDE FORMATION IN COAL FLAMES [J].

KRAMLICH, JC ;

COLE, JA ;

MCCARTHY, JM ;

LANIER, WS ;

MCSORLEY, JA .

COMBUSTION AND FLAME, 1989, 77 (3-4) :375-384

[18]

Liljedahl GN, 2006, 31 INT TECHN C COAL

[19] PARAMETRIC STUDY OF N2O FORMATION IN COAL COMBUSTION [J].

LOHUIS, JAO ;

TROMP, PJJ ;

MOULIJN, JA .

FUEL, 1992, 71 (01) :9-14

[20] Experimental programme in CIUDEN's CO2 capture technology development plant for power generation [J].

Lupion, M. ;

Nauarrete, B. ;

Otero, P. ;

Cortes, V. J. .

CHEMICAL ENGINEERING RESEARCH & DESIGN, 2011, 89 (09) :1494-1500

← 1 2 3 →