Total synthesis of sesterterpenoids

被引：31
|
作者：
Chen, Yuye [1 ,2 ,3 ]
Zhao, Jing [1 ]
Lia, Shaoping [1 ]
Xu, Jing [2 ,3 ]
机构：
[1] Univ Macau, Inst Chinese Med Sci, State Key Lab Qual Res Chinese Med, Macau, Peoples R China
[2] Southern Univ Sci & Technol, Dept Chem, Shenzhen, Guangdong, Peoples R China
[3] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China
来源：
NATURAL PRODUCT REPORTS | 2019年 / 36卷 / 02期
基金：
中国国家自然科学基金;
关键词：
ASYMMETRIC TOTAL-SYNTHESIS; DIASTEREOSELECTIVE TOTAL-SYNTHESIS; PAUSON-KHAND REACTION; CARBON BOND FORMATION; SAMARIUM(II)-MEDIATED 4-EXO-TRIG CYCLIZATION; FURANOSESTERTERPENE NATURAL-PRODUCT; CATALYTIC EPOXYPOLYENE CYCLIZATION; ENHANCED AMPHIPHILIC CHARACTER; SYNCYTIUM FORMATION INHIBITOR; TRANSITION-METAL CATALYSIS;
D O I：
10.1039/c8np00050f
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Sesterterpenoids are a small family of terpenes that often possess intriguing biological profiles and complicated chemical structures. Their total syntheses are usually remarkably challenging, requiring methodological and strategic innovation. In this review, we summarize and discuss the total syntheses of sesterterpenoids published during the coverage period, and the key chemical transformations are highlighted.
引用
收藏
页码：263 / 288
页数：26
相关论文
共 50 条
  • [31] Important sedimentary sesterterpenoids from the diatom Pleurosigma intermedium
    Belt, ST
    Allard, G
    Massé, G
    Robert, JM
    Rowland, S
    CHEMICAL COMMUNICATIONS, 2000, (06) : 501 - 502
  • [32] A Unified Approach to trans-Hydrindane Sesterterpenoids
    Hog, Daniel T.
    Mayer, Peter
    Trauner, Dirk
    JOURNAL OF ORGANIC CHEMISTRY, 2012, 77 (13): : 5838 - 5843
  • [33] A new family of sesterterpenoids isolated around the Pacific Rim
    Shirley, Harry J.
    Jamieson, Megan L.
    Brimble, Margaret A.
    Bray, Christopher D.
    NATURAL PRODUCT REPORTS, 2018, 35 (03) : 210 - 219
  • [34] Selenium dioxide promoted selenylation/cyclization of leucosceptrane sesterterpenoids
    Geng, Hao
    Fu, Ran
    Zhou, Ting-Ting
    Li, Man
    Liu, Yan-Chun
    Li, Xiao-Nian
    Liu, Yan
    Zheng, Yu
    Li, Sheng-Hong
    CHEMICAL COMMUNICATIONS, 2024, 60 (76) : 10512 - 10515
  • [35] New cytotoxic sesterterpenoids from the nudibranch Chromodoris inornata
    Miyamoto, T
    Sakamoto, K
    Amano, H
    Arakawa, Y
    Nagarekawa, Y
    Komori, T
    Higuchi, R
    Sasaki, T
    TETRAHEDRON, 1999, 55 (30) : 9133 - 9142
  • [36] Targeting cancer with sesterterpenoids: the new potential antitumor drugs
    Zhang, Caiguo
    Liu, Yan
    JOURNAL OF NATURAL MEDICINES, 2015, 69 (03) : 255 - 266
  • [37] Cytotoxic Sesterterpenoids from Bornean Sponge Spongia sp
    Phan, Chin-Soon
    Kamada, Takashi
    Hamada, Toshiyuki
    Vairappan, Charles S.
    RECORDS OF NATURAL PRODUCTS, 2018, 12 (06) : 643 - 647
  • [38] Convergency and divergency as strategic elements in total synthesis:: The total synthesis of (-)-drupacine and the formal total synthesis of (±)-Cephalotaxine, (-)-cephalotaxine, and (+)-cephalotaxine
    Liu, Qi
    Ferreira, Eric M.
    Stoltz, Brian M.
    JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (19): : 7352 - 7358
  • [39] Configurations of polyunsaturated sesterterpenoids from the diatom, Haslea ostrearia
    Johns, L
    Belt, S
    Lewis, CA
    Rowland, S
    Massé, G
    Robert, JM
    König, WA
    PHYTOCHEMISTRY, 2000, 53 (05) : 607 - 611
  • [40] Targeting cancer with sesterterpenoids: the new potential antitumor drugs
    Caiguo Zhang
    Yan Liu
    Journal of Natural Medicines, 2015, 69 : 255 - 266
12345