Total synthesis of sesterterpenoids

被引:31
|
作者
Chen, Yuye [1 ,2 ,3 ]
Zhao, Jing [1 ]
Lia, Shaoping [1 ]
Xu, Jing [2 ,3 ]
机构
[1] Univ Macau, Inst Chinese Med Sci, State Key Lab Qual Res Chinese Med, Macau, Peoples R China
[2] Southern Univ Sci & Technol, Dept Chem, Shenzhen, Guangdong, Peoples R China
[3] Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
ASYMMETRIC TOTAL-SYNTHESIS; DIASTEREOSELECTIVE TOTAL-SYNTHESIS; PAUSON-KHAND REACTION; CARBON BOND FORMATION; SAMARIUM(II)-MEDIATED 4-EXO-TRIG CYCLIZATION; FURANOSESTERTERPENE NATURAL-PRODUCT; CATALYTIC EPOXYPOLYENE CYCLIZATION; ENHANCED AMPHIPHILIC CHARACTER; SYNCYTIUM FORMATION INHIBITOR; TRANSITION-METAL CATALYSIS;
D O I
10.1039/c8np00050f
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Sesterterpenoids are a small family of terpenes that often possess intriguing biological profiles and complicated chemical structures. Their total syntheses are usually remarkably challenging, requiring methodological and strategic innovation. In this review, we summarize and discuss the total syntheses of sesterterpenoids published during the coverage period, and the key chemical transformations are highlighted.
引用
收藏
页码:263 / 288
页数:26
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