Real-time mechanistic monitoring of an acetal hydrolysis using ultrafast 2D NMR

被引：29
|
作者：
Queiroz, Luiz H. K., Jr. [1 ,2 ]
Giraudeau, Patrick [3 ]
dos Santos, Fabiane A. B. [1 ]
de Oliveira, Kleber T. [1 ]
Ferreira, Antonio G. [1 ]
机构：
[1] Univ Fed Sao Carlos UFSCar, Dept Quim, Lab Ressonancia Magnet Nucl, BR-13565905 Sao Carlos, SP, Brazil
[2] Univ Fed Goias, Inst Quim, Lab Ressonancia Magnet Nucl, Goiania, Go, Brazil
[3] Univ Nantes, CNRS, UMR 6230, Nantes, France
来源：
MAGNETIC RESONANCE IN CHEMISTRY | 2012年 / 50卷 / 07期
基金：
巴西圣保罗研究基金会;
关键词：
NMR; 1H; 13C; ultrafast NMR; NMR theoretical calculations; acetal hydrolysis; hemiacetal intermediate; SPECTROSCOPY; SENSITIVITY;
D O I：
10.1002/mrc.3827
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ultrafast (UF) 2D NMR makes it possible to obtain a 2D NMR spectrum in less than a second. Here, UF-HSQC experiments are used for the real-time mechanistic study of an acetal hydrolysis at C-13 natural abundance, and it is possible to characterize the presence of the hemiacetal, an intermediate with a well-known short lifetime. The assignments are confirmed and rationalized by quantum calculations of H-1 and C-13 NMR chemical shifts and natural bonding orbital analysis. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码：496 / 501
页数：6
相关论文
共 50 条
  • [31] An improved ultrafast 2D NMR experiment: Towards atom-resolved real-time studies of protein kinetics at multi-Hz rates
    Gal, Maayan
    Kern, Thomas
    Schanda, Paul
    Frydman, Lucio
    Brutscher, Bernhard
    JOURNAL OF BIOMOLECULAR NMR, 2009, 43 (01) : 1 - 10
  • [32] An improved ultrafast 2D NMR experiment: Towards atom-resolved real-time studies of protein kinetics at multi-Hz rates
    Maayan Gal
    Thomas Kern
    Paul Schanda
    Lucio Frydman
    Bernhard Brutscher
    Journal of Biomolecular NMR, 2009, 43 : 1 - 10
  • [33] 2D layered Mn and Ru oxide nanosheets for real-time breath humidity monitoring
    Choi, Seon-Jin
    Kim, Il-Doo
    Park, Hee Jung
    APPLIED SURFACE SCIENCE, 2022, 573
  • [34] Real-Time Body Pose Recognition Using 2D or 3D Haarlets
    Michael Van den Bergh
    Esther Koller-Meier
    Luc Van Gool
    International Journal of Computer Vision, 2009, 83 : 72 - 84
  • [35] Real-Time Body Pose Recognition Using 2D or 3D Haarlets
    Van den Bergh, Michael
    Koller-Meier, Esther
    Van Gool, Luc
    INTERNATIONAL JOURNAL OF COMPUTER VISION, 2009, 83 (01) : 72 - 84
  • [36] Real-time visualization using a 2D/3D imaging MMWave radar
    Takács, B
    Sadovnik, L
    Manasson, V
    Wade, M
    Klein, LA
    Wong, D
    Kiss, B
    Benedek, B
    Szijarto, G
    REAL-TIME IMAGING VIII, 2004, 5297 : 101 - 105
  • [37] Real-time 2D to 3D video conversion
    Ianir Ideses
    Leonid P. Yaroslavsky
    Barak Fishbain
    Journal of Real-Time Image Processing, 2007, 2 : 3 - 9
  • [38] Real-time 2D to 3D video conversion
    Ideses, Ianir
    Yaroslavsky, Leonid P.
    Fishbain, Barak
    JOURNAL OF REAL-TIME IMAGE PROCESSING, 2007, 2 (01) : 3 - 9
  • [39] Evaluation of Ultrafast 2D NMR for Quantitative Analysis
    Giraudeau, Patrick
    Remaud, Gerald S.
    Akoka, Serge
    ANALYTICAL CHEMISTRY, 2009, 81 (01) : 479 - 484
  • [40] Line shape considerations in ultrafast 2D NMR
    Shapira, B
    Lupulescu, A
    Shrot, Y
    Frydman, L
    JOURNAL OF MAGNETIC RESONANCE, 2004, 166 (02) : 152 - 163
12345